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Electronic properties of M2InV3O11 (M(II) = Zn(II) and Co(II)) compounds

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Materials Science-Poland

Abstract

The electronic properties of multicomponent vanadate oxides M2InV3O11 (M(II) = Zn(II) and Co(II)) were investigated by electrical resistivity and electron paramagnetic resonance (EPR) measurements. Replacement of non-magnetic Zn(II) cations with magnetic Co(II) ions resulted in a significant drop in the electrical conductivity and an increase in the activation energy. The EPR spectroscopy revealed the presence of VO2+ vanadyl ions in both compounds, while the presence of divalent cobalt ions was identified in the Co2InV3O11 oxide at low temperatures. The concentration of VO2+ vanadyl ions was found to be about one order higher for the vanadate oxide without magnetic ions. It is suggested that the increased concentration of VO2+ ions could be responsible for the enhanced conductivity of Zn2InV3O11.

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Authors and Affiliations

  1. Department of Solid State Physics, School of Physics, Faculty of Sciences, University of Athens, Panepistimiopolis, 15 784, Zografos, Athens, Greece

    N. Guskos, S. Glenis & K. Karkas

  2. Institute of Physics, West Pomeranian University of Technology, Al. Piastow 17, 70-310, Szczecin, Poland

    N. Guskos & G. Zolnierkiewicz

  3. Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Al. Piastow 17, 70-310, Szczecin, Poland

    M. Bosacka

Authors
  1. N. Guskos
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  2. S. Glenis
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  3. K. Karkas
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  4. G. Zolnierkiewicz
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  5. M. Bosacka
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Corresponding author

Correspondence to N. Guskos.

Additional information

This paper was presented at the Conference Functional and Nanostructured Materials, FNMA 11, 6–9 September 2011, Szczecin, Poland

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Guskos, N., Glenis, S., Karkas, K. et al. Electronic properties of M2InV3O11 (M(II) = Zn(II) and Co(II)) compounds. Mater Sci-Pol 31, 25–28 (2013). https://doi.org/10.2478/s13536-012-0067-3

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  • DOI: https://doi.org/10.2478/s13536-012-0067-3

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