Anthocyanins present in the grapes of nine grapevine (Vitis vinifera L.) varieties and ten interspecific hybrids were compared. Total anthocyanin levels were determined in fresh grapes and the values ranged from 0.50 g kg−1 to 4.99 g kg−1. A total of twenty-two different anthocyanins were identified. Malvidin 3-glucoside was the most abundant anthocyanin, with concentrations ranging from 30 % to 64 % of the totals observed. The ratio of acetylated to coumaroylated malvidin and peonidin derivatives ranged from 0.09 (variety: Regent) to 1.34 (variety: Cerason), depending on the variety. Diglucosylated anthocyanins were not found in particular interspecific hybrids such as the teinturier XIV 26–56, Laurot, Merlan, and Nativa.
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Alcalde-Eon, C., Escribano-Bailón, M. T., Santos-Buelga, C., & Rivas-Gonzalo, J. C. (2006). Changes in the detailed pigment composition of red wine during maturity and ageing. A comprehensive study. Analytica Chimica Acta, 563, 238–254. DOI: 10.1016/j.aca.2005.11.028.
Brar, H. S., Singh, Z., & Swinny, E. (2008). Dynamics of anthocyanin and flavonol profiles in the ‘Crimson Seedless’ grape berry skin during development and ripening. Scientia Horticulturae, 117, 349–356. DOI: 10.1016/j.scienta.2008.05.007.
Burns, J., Mullen, W., Landrault, N., Teissedre, P. L., Lean, M. E. J., & Crozier, A. (2002). Variations in the profile and content of anthocyanins in wines made from Cabernet Sauvignon and hybrid grapes. Journal of Agricultural and Food Chemistry, 50, 4096–4102. DOI: 10.1021/jf011233s.
De Rosso, M., Tonidandel, L., Larcher, R., Nicolini, G., Ruggeri, V., Dalla Vedova, A., De Marchi, F., Gardiman, M., & Flamini, R. (2012). Study of anthocyanic profiles of twentyone hybrid grape varieties by liquid chromatography and precursor-ion mass spectrometry. Analytica Chimica Acta, 732, 120–129. DOI: 10.1016/j.aca.2011.10.045.
Downey, M. O., Dokoozlian, N. K., & Krstic, M. P. (2006). Cultural practice and environmental impacts on the flavonoid composition of grapes and wine: A review of recent research. American Journal of Enology and Viticulture, 57, 257–268.
Drdak, M., Altamirano, R. C., Rajniakova, A., Simko, P., Malik, F., Balik, J., & Benkovska, D. (1991). Vorkommen von Anthocyan-Farbstoffen in blauen Traubensorten. Mitteilungen Klosterneuburg, 41, 190–193. (in German)
Fernández-López, J. A., Hidalgo, V., Almela, L., & López Roca, J. M. (1992). Quantitative changes in anthocyanin pigments of Vitis vinifera cv monastrell during maturation. Journal of the Science of Food and Agriculture, 58, 153–155. DOI: 10.1002/jsfa.2740580127.
Fuleki, T., & Francis, F. J. (1968). Quantitative methods for anthocyanins. 2. Determination of total anthocyanin and degradation index for cranberry juice. Journal of Food Science, 33, 78–83. DOI: 10.1111/j.1365-2621.1968.tb00888.x.
García-Beneytez, E., Revilla, E., & Cabello, F. (2002). Anthocyanin pattern of several red grape cultivars and wines made from them. European Food Research and Technology, 215, 32–37. DOI: 10.1007/s00217-002-0526-x.
García-Beneytez, E., Cabello, F., & Revilla, E. (2003). Analysis of grape and wine anthocyanins by HPLC-MS. Journal of Agricultural and Food Chemistry, 51, 5622–5629. DOI: 10.1021/jf0302207.
Goldy, R. G., Ballinger, W. E., & Maness, E. P. (1986). Fruit anthocyanin content of some Euvitis × Vitis rotundifolia hybrids. Journal of the American Society for Horticultural Science, 111, 955–960.
González-Neves, G., Franco, J., Barreiro, L., Gil, G., Moutounet, M., & Carbonneau, A. (2007). Varietal differentiation of Tannat, Cabernet-Sauvignon and Merlot grapes and wines according to their anthocyanic composition. European Food Research and Technology, 225, 111–117. DOI: 10.1007/s00217-006-0388-8.
González-SanJosé, M. L., & Diez, C. (1992). Relationship between anthocyanins and sugars during the ripening of grape berries. Food Chemistry, 43, 193–197. DOI: 10.1016/0308-8146(92)90172-x.
He, J. J., Liu, Y. X., Pan, Q. H., Cui, X. Y., & Duan, C. Q. (2010). Different anthocyanin profiles of the skin and the pulp of Yan73 (Muscat Hamburg × Alicante Bouschet) grape berries. Molecules, 15, 1141–1153. DOI: 10.3390/molecules15031141.
Hebrero, E., Garcia-Rodriguez, C., Santos-Buelga, C., & Rivas-Gonzalo, J. C. (1989). Analysis of anthocyanins by high perfomance liquid chromatography-diode array spectroscopy in a hybrid grape variety (Vitis vinifera × Vitis berlandieri 41B). American Journal of Enology and Viticulture, 40, 283–291.
Katalinić, V., Smole Možina, S., Skroza, D., Generalić, I., Abramovič, H., Miloš, M., Ljubenkov, I., Piskernik, S., Pezo, I., Terpinc, P., & Boban, M. (2010). Polyphenolic profile, antioxidant properties and antimicrobial activity of grape skin extracts of 14 Vitis vinifera varieties grown in Dalmatia (Croatia). Food Chemistry, 119, 715–723. DOI: 10.1016/j.foodchem.2009.07.019.
Kozma, P., Jr. (2000). Winegrape breeding for fungus disease resistance. Acta Horticulturae, 528, 511–516.
Lamikanra, O. (1989). Anthocyanins of Vitis rotundifolia hybrid grapes. Food Chemistry, 33, 225–237. DOI: 10.1016/0308-8146(89)90016-2.
Manns, D. C., & Mansfield, A. K. (2012). A core-shell column approach to a comprehensive high-performance liquid chromatography phenolic analysis of Vitis vinifera L. and interspecific hybrid grape juices, wines, and other matrices following either solid phase extraction or direct injection. Journal of Chromatography A, 1251, 111–121. DOI: 10.1016/j.chroma.2012.06.045.
Mazza, G., & Francis, F. J. (1995). Anthocyanins in grapes and grape products. Critical Reviews in Food Science and Nutrition, 35, 341–371. DOI: 10.1080/10408399509527704.
Mazzuca, P., Ferranti, P., Picariello, G., Chianese, L., & Addeo, F. (2005). Mass spectrometry in the study of anthocyanins and their derivatives: differentiation of Vitis vinifera and hybrid grapes by liquid chromatography/electrospray ionization mass spectrometry and tandem mass spectrometry. Journal of Mass Spectrometry, 40, 83–90. DOI: 10.1002/jms.778.
Mori, K., Sugaya, S., & Gemma, H. (2005). Decreased anthocyanin biosynthesis in grape berries grown under elevated night temperature condition. Scientia Horticulturae, 105, 319–330. DOI: 10.1016/j.scienta.2005.01.032.
Orak, H. H. (2007). Total antioxidant activities, phenolics, anthocyanins, polyphenoloxidase activities of selected red grape cultivars and their correlations. Scientia Horticulturae, 111, 235–241. DOI: 10.1016/j.scienta.2006.10.019.
Papouškovřávek, J., Balík, J., Myjavcová, R., Barták, P., Tománkova, E., & Lemr, K. (2011). Advanced liquid chromatography/mass spectrometry profiling of anthocyanins in relation to set of red wine varieties certified in Czech Republic. Journal of Chromatography A, 1218, 7581–7591. DOI: 10.1016/j.chroma.2011.07.027.
Revilla, E., García-Beneytez, E., Cabello, F., Martín-Ortega, G., & Ryan, J. M. (2001). Value of high-performance liquid chromatographic analysis of anthocyanins in the differentiation of red grape cultivars and red wines made from them. Journal of Chromatography A, 915, 53–60. DOI: 10.1016/s0021-9673(01)00635-5.
Revilla, E., García-Beneytez, E., & Cabello, F. (2009). Anthocyanin fingerprint of clones of Tempranillo grapes and wines made with them. Australian Journal of Grape and Wine Research, 15, 70–78. DOI: 10.1111/j.1755-0238.2008.00037.x.
Timberlake, C. F. (1980). Anthocyanins-occurence, extraction and chemistry. Food Chemistry, 5, 69–80. DOI: 10.1016/ 0308-8146(80)90065-5.
Zhao, Q., Duan, C. Q., & Wang, J. (2010). Anthocyanins profile of grape berries of Vitis amurensis, its hybrids and their wines. International Journal of Molecular Sciences, 11, 2212–2228. DOI: 10.3390/ijms11052212.
Zhu, L., Zhang, Y., & Lu, J. (2012). Phenolic contents and composition in skins of red wine grape cultivars mong various genetic backgrounds and originations. International Journal of Molecular Sciences, 13, 3492–3510. DOI: 10.3390/ijms13033492.
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Balík, J., Kumšta, M. & Rop, O. Comparison of anthocyanins present in grapes of Vitis vinifera L. varieties and interspecific hybrids grown in the Czech Republic. Chem. Pap. 67, 1285–1292 (2013). https://doi.org/10.2478/s11696-013-0378-9
- Vitis vinifera L.
- interspecific hybrids