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ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon

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Abstract

MW ArF laser irradiation of gaseous cis-dichloroethene results in fast decomposition of this compound and in deposition of solid ultrafine Cl- and H-containing carbonaceous powder which is of interest due to its sub-microscopic structure and possible reactive modification of the C-Cl bonds. The product was characterized by electron microscopy, and FTIR and Raman spectra and it was revealed that HCl, H2, and C/H fragments are lost and graphitic features are adopted upon heating to 700°C.

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Authors and Affiliations

  1. Laboratory of Laser Chemistry, Institute of Chemical Process Fundamentals, ASCR, 16502, Prague, Czech Republic

    Josef Pola & Anna Galíková

  2. Institute of Inorganic Chemistry, ASCR, 25068, Řež, Czech Republic

    Jan Šubrt

  3. National Institute of Advanced Industrial Science and Technology, AIST Tsukuba, Ibaraki, 305-8565, Japan

    Akihiko Ouchi

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  1. Josef Pola
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  2. Anna Galíková
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  3. Jan Šubrt
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  4. Akihiko Ouchi
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Correspondence to Josef Pola or Akihiko Ouchi.

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Pola, J., Galíková, A., Šubrt, J. et al. ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon. Chem. Pap. 64, 625–629 (2010). https://doi.org/10.2478/s11696-010-0048-0

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