Abstract
The electrochemical behaviour of the LiF-La2O3 and LiF-CaF2-La2O3 systems was investigated by means of cyclic voltammetry. Several types of working electrodes (spectrographic pure graphite, W, Mo, Ni, Cu) were used. It was found that chemical reactions take place in the system during the dissolution of lanthanum oxide. The reduction of lithium cations occurred at the most positive potential from the species formed in the melt on ‘inert’ cathodes (W, Mo). The reactive cathodes (Cu, Ni) allowed the lanthanum deposition with depolarisation.
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Ambrová M., Danielik, V., & Jurišová, J. (2007a). Electrode-position of lanthanum from molten alkali fluorides. In Proceedings of International Youth Conference on Energetics, May 31–June 2, 2007 (pp. 209–210). Budapest, Hungary: Budapest University of Technology and Economics.
Ambrová, M., Jurišová, J., Danielik, V., & Gabčová, J. (2007b). On the solubility of lanthanum oxide in molten alkali fluorides, Journal of Thermal Analysis and Calorimetry, in press. DOI: 10.1007/s10973-007-8533-6.
Berul, S. I., & Voskresenskaya, N. K. (1963). The reactions between CeO2, NdO3, SmO3, and molten fluorides. Zhurnal Neorganicheskoi Khimii, 8, 1431–1436.
Caravaca, C., de Córdoba, G., Tomás, M. J., & Rosado, M. (2007). Electrochemical behaviour of gadolinium ion molten LiCl-KCl eutectic. Journal of Nuclear Materials, 360, 25–31. DOI: 10.1016/j.jnucmat.2006.08.009.
Castrillejo, Y., Bermejo, M. R., Martínez, A. M., Barrado, E. & Díaz Arocas, P. (2007). Application of electrochemical techniques in pyrochemical processes. — Electrochemical behaviour of rare earths at W, Cd, Bi, and Al electrodes. Journal of Nuclear Materials, 360, 32–42. DOI: 10.1016/j.jnucmat.2006.08.011.
Chamelot, P., Massot, L., Hamel, C., Nourry, C., & Taxil, P. (2005). Feasibility of the electrochemical separation of An, Ln, solvent in molten fluorides. In Proceedings of 7th International Symposium on Molten Salts Chemistry & Technology, August 29–September 2, 2005 (Vol. II, pp. 615–618). Toulouse, France: University Paul-Sabatier of Toulouse III.
Chamelot, P., Massot, L., Hamel, C., Nourry, C., & Taxil, P. (2007). Feasibility of the electrochemical way in molten fluorides for separating thorium and lanthanides and extracting lanthanides from the solvent. Journal of Nuclear Materials, 360, 64–74. DOI: 10.1016/j.jnucmat.2006.08.015.
Chase M. W. (1998). NIST-JANAF, Thermo chemical tables (4rd ed.). Malville NY: NIST.
Fedorov, P. P. (1999). Systems of alkali and rare-earth metal fluorides. Zhurnal Neorganicheskoi Khimii, 44, 1703–1727.
Hamel, C., Chamelot, P., & Taxil, P. (2004). Neodymium(III) cathodic processes in molten fluorides. Electrochimica Acta, 49, 4467–4476. DOI: 10.1016/j.electacta.2004.05.003.
Massalski, T., & Okamoto, H. (Eds.) (1990). Binary alloy phase diagrams (2nd ed.). Materials Park, Ohio: ASM International.
Massot, L., Chamelot, P., & Taxil, P. (2005a). Electrochemical reduction of samarium(III) in LiF-CaF2 media. In Proceedings of 7th International Symposium on Molten Salts Chemistry & Technology, August 29–September 2, 2005 (Vol. II, pp. 685–688). Toulouse, France: University Paul-Sabatier of Toulouse III.
Massot, L., Chamelot, P., & Taxil, P. (2005b). Cathodic behaviour of samarium(III) in LiF-CaF2 media on molybdenum and nickel electrodes. Electrochimica Acta, 50, 5510–5517. DOI: 10.1016/j.electacta.2005.03.046.
Stefanidaki, E., Hasiotis, C., & Kontoyannis, C. (2001). Electrodeposition of neodymium from LiF-NdF3-Nd2O3 melts. Electrochimica Acta, 46, 2665–2670. DOI: 10.1016/S0013-4686(01)00489-3.
Taxil, P. (1985). Formation d’alliages tantale-nickel par voie électrochimique. Journal of the Less-Common Metals, 113, 89–101. DOI: 10.1016/0022-5088(85)90151-1.
Taxil, P., Chamelot, P., Massot, L., & Hamel, C. (2003). Electrodeposition of alloys or compounds in molten salts and applications. Journal of Mining and Metallurgy, Section B: Metallurgy, 39, 177–200.
van der Meer, J. P. M., Konings, R. J. M., Jacobs, M. H. G., & Oonk, H. A. J. (2004). Thermodynamic modelling of LiF-LnF3 and LiF-AnF3 phase diagrams. Journal of Nuclear Materials, 335, 345–352. DOI: 10.1016/j.jnucmat.2004.07.035.
Wikipedia, Retrieved May, 2007, from http://en.wikipedia.org.
Yamamura, T., Songyu, Z., Nehmood, M., Hongmin, Z., Ichi-nohe, T., Xin-Ing, G., Sato, Y., Maekawa, H., Hoshi, M., Mizuguchi, H., Arie, K., & Fujita, R. (2005). Electrochemical behaviour of rare earth and rhodium containing species in molten alkali chlorides. In Proceedings of 7th International Symposium on Molten Salts Chemistry & Technology, August 29–September 2, 2005 (Vol. II, pp. 611–614). Toulouse, France: University Paul-Sabatier of Toulouse III.
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Ambrová, M., Jurišová, J., Sýkorová, A. et al. Electrochemical behaviour of the LiF-(CaF2)-La2O3 system. Chem. Pap. 62, 154–159 (2008). https://doi.org/10.2478/s11696-008-0005-3
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DOI: https://doi.org/10.2478/s11696-008-0005-3