Abstract
The stability change of nickel(II) ion complexes including one and two nicotinamide (B3 vitamin) molecules in aqueous dimethyl sulfoxide (XDMSO = 0–0.85 m.f.) was studied at 298.2±0.1 K and 0.25 ionic strength value (NaClO4) using the potentiometric method. The first stage constant of complexation increased until organic solvent concentration was 0.5 m.f. and reduced at higher DMSO content. The difference between complex and central ions solvation is a dominating contribution into the Gibbs energy change of mononicotinamide complex formation reaction. When the second ligand molecule was bonded into the coordination compound, the nicotinamide contribution to ΔtrGr rose and became prevailing at XDMSO = 0.7–0.85. The ligand was found to replace a water molecule in the coordination sphere of the cation according to spectrophotometric study results.
This is a preview of subscription content, log in via an institution to check access.
References
J.C. Fontecilla-Camp, In: M.J. Clarke, J.B. Goodenough, C.K. Jørgensen, D.M.P. Mingos, G.A. Palmer, P.J. Sadler, R. Weiss, R.J.P. Williams (Eds.), Bioinorganic Chemistry. Structure and Bonding (Springer-Verlag, Berlin and Heidelberg, 1998) Vol.91, 1
R.K. Thauer, G. Diekert, P. Schonheit, Trends Biochem. Sci. 5, 304 (1980)
J.P. Thyssen, A. Linneberg, T. Menné, J.D. Johansen, Contact Dermatitis 57, 287 (2007)
K.S. Kasprzak, F.W. Sunderman Jr., K. Salnikow, Mutation Res. 533, 67 (2003)
J.K. Dunnick, M.R. Elwell, A.E. Radovsky, J.M. Benson, F.F. Hahn, K.J. Nikula, E.B. Barr, C.H. Hobbs, Cancer Res. 55, 5251 (1995)
E.A. Stroyev, Biologic chemistry (Vysshaya shkola, Moscow, 1986) (in Russian)
M.M. Azizov, A. Kushakbaev, N.A. Parpiev, Zhurn. Koord. Khim. 6, 1221 (1980) (in Russian)
J.R. Allan, N.D. Baird, A.L. Kassyk, J. Therm. Anal. 16, 79 (1979)
C. Semiha, B. Ender, A. Katsuyuki, C. Emine, Cryst. Res. Technol. 41, 314 (2006)
S.C. Mojumdar, I. Ondrejkovicova, L. Nevidanska, M. Melnik, J. Anal. Appl. Pyr. 64, 59 (2002)
F.A. Al-Saif, M.S. Refat, J. Mol. Struct. 1021, 40 (2012)
K.V. Grazhdan, N.N. Kuranova, S.V. Dushina, V.A. Sharnin, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhn. 51, 30 (2008) (in Russian)
K.V. Grazhdan, G.A. Gamov, S.V. Dushina, V.A. Sharnin, Russ. J. Coord. Chem. 35, 912 (2009)
V.A. Borodin, V.P. Vasil’ev, E.V. Kozlovskii, Zhurn. Neorg. Khim. 31, 10 (1986) (in Russian)
V.P. Vasil’ev, V.A. Borodin, E.V. Kozlovskii, Computers’ application for calculations in analytical chemistry (Vysshaya shkola, Moscow, 1993) (in Russian)
V.O. Reikhsfel’d, V.L. Ruban, I.E. Saratov, V.V. Korol’ko, Laboratory works on the technology of basic organic synthesis (Khimia, Moscow, 1966) (in Russian)
V.M. Peshkova, V.M. Savostina, Analytical chemistry of nickel (Nauka, Moscow, 1966) (in Russian)
V.I. Minkin, B.Ya. Simkin, R.M. Minyaev, Theory of molecular structure (Phoenix, Rostov-upon-Don, 1997) (in Russian).
A.F. Borina, Russ. J. Coord. Chem. 33, 831 (2007)
F.V. Devyatov, V.F. Safina, L.G. Lazareva, Yu.I. Sal’nikov, Zhurn. Neorg. Khim. 38, 1085 (1993) (in Russian)
V.V. Matveev, Sov. J. Struct. Chem. 21, 487 (1980)
M.A. Zevakin, K.V. Grazhdan, S.V. Dushina, V.A. Sharnin, Drugs of the Future 32Suppl. A, 87 (2007)
S.V. Dushina, V.A. Sharnin, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhn. 56, 3 (2013) (in Russian)
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Gamov, G., Dushina, S., Sharnin, V. et al. Complexation of nickel (II) ion with B3 vitamin in aqueous dimethyl sulfoxide. cent.eur.j.chem. 11, 1959–1963 (2013). https://doi.org/10.2478/s11532-013-0325-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2478/s11532-013-0325-1