Skip to main content
SpringerLink
Log in

Synthesis, crystal structure, spectroscopic and thermal investigations of neodymium(III) biphenyl-4,4′-dicarboxylate framework

  • Research Article
  • Published:
Central European Journal of Chemistry

Abstract

The three-dimensional complex {[Nd(bpdc)1.5(DMF)]·1.4DMF}n (DMF=N,N′-dimethylformamide, bpdc=biphenyl-4,4′-dicarboxylate) was synthesized using the solvothermal method. The crystal structure of the neodymium(III) complex has been determined by single-crystal X-ray diffraction method at 100(2) K. The polymeric structure consists of neodymium polyhedra bridged by bpdc ligands. Eight-coordinated Nd(III) atoms are surrounded by seven oxygen atoms from six bpdc moieties and one oxygen atom from the DMF molecule. The 3D structure of the complex contains two types of channels occupied by DMF molecules. Thermal analysis revealed that DMF molecules are lost in a stepwise manner. The infrared spectrum confirmed full deprotonation of acid and presence of DMF molecules in the structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. Qiu, G. Zhu, Coord. Chem. Rev. 253, 2891 (2009)

    Article  CAS  Google Scholar 

  2. X. Li, Y.Q. Zou, J. Coord. Chem. 59(10) 1131 (2006)

    Article  Google Scholar 

  3. M. Eddaoudi, H. Li, O.M. Yaghi, J. Am. Chem. Soc. 122, 1391 (2000)

    Article  CAS  Google Scholar 

  4. A. Michaelides, S. Skoulika, Cryst. Growth Des. 5, 529 (2005)

    Article  CAS  Google Scholar 

  5. X. Li, Y. Wang, Z. Ma, R. Hang, J. Zhao, J. Coord. Chem. 63, 1029 (2010)

    Article  CAS  Google Scholar 

  6. Z.Y. Fu, S.M. Hu, W.X. Du, J.J. Zhang, S.Ch. Xiang, X.T. Wu, Chin. J. Struct. Chem. 23, 176 (2004)

    CAS  Google Scholar 

  7. X.J. Luan, X.H. Cai, Y.Y. Wang, D.S. Li, C.J. Wang, P. Liu, H.M. Hu, Q.Z. Shi, S.M. Peng, Chem. Eur. J. 12, 6281 (2008)

    Article  Google Scholar 

  8. S.Y. Zhang, M.X. Yu, L.G. Zhu, J. Mol. Struc. 699, 101 (2004)

    Article  CAS  Google Scholar 

  9. Ch.L. Yuan, Acta Cryst. E63, m3147 (2007)

    CAS  Google Scholar 

  10. G.A. Santillan, C.J. Carrano, Inorg. Chem. 47, 930 (2008)

    Article  CAS  Google Scholar 

  11. X. Shi, G. Zhu, X. Wang, G. Li, Q. Fang, GanGwu, G. Tian, M. Xue, X. Zhao, R. Wang, Qiu, Cryst. Growth Des. 5, 207 (2005)

    Article  CAS  Google Scholar 

  12. K.O. Kongshaug, H. Fjellvag, J. Solid State Chem. 175, 182 (2003)

    Article  CAS  Google Scholar 

  13. L. Zhou, Y. Wang, C. Zhou, C. Wang, Q. Shi, S. Peng, Cryst. Growth Des. 7, 300 (2007)

    Article  CAS  Google Scholar 

  14. Ch.B. Ma, Ch.N. Chen, Q.T. Liu, CrystEngCommun. 7, 650 (2005)

    Article  CAS  Google Scholar 

  15. H.R. Moon, J.H. Kim, M.P. Sun, Angew. Chem. Int. Ed. 44, 1261 (2005)

    Article  CAS  Google Scholar 

  16. L. Pan, N. Ching, X. Huang, J. Li, Inorg. Chem. 39, 5333 (2000)

    Article  CAS  Google Scholar 

  17. J.J. Wang, Y.Ch. Cui, G.G. Gao, R.Z. Wang, B. Liu, X.M. Wang, Chin. J. Struct. Chem. 27, 1149 (2008)

    CAS  Google Scholar 

  18. Z.Y. Fu, X.T. Wu, J.C. Dai, S.M. Hu, W.X. Du, New J. Chem. 26, 978 (2002)

    Article  CAS  Google Scholar 

  19. G.F. Liu, B.H. Ye, Y.H. Ling, X.M. Chen, Chem. Commun. 1442 (2002)

  20. Z.D. Liu, H.L. Zhu, Acta Cryst. E60, m1866 (2004)

    CAS  Google Scholar 

  21. X.H. Li, S.Z. Yang, H.P. Xiao, Cryst. Growth Des. 6, 2329 (2006)

    Google Scholar 

  22. M.R. Montney, R.M. Supkowski, R.L. LaDuca, CrystEngCommun. 10, 111 (2008)

    Article  CAS  Google Scholar 

  23. B. Yu, X.Q. Wang, H.Z. Kou, G.Q. Shen, D.Z. Shen, Acta Cryst. E62, m3078 (2006)

    CAS  Google Scholar 

  24. Y. Liang, M. Hong, R. Cao, J. Weng, W. Su, Inorg. Chem. Commun. 4, 599 (2001)

    Article  CAS  Google Scholar 

  25. Y.B. Wang, W.J. Zhuang, L.P. Jin, S.Z. Lu, J. Mol. Struc. 705, 21 (2004)

    Article  CAS  Google Scholar 

  26. X.L. Wang, Y.F. Bi, G.Ch. Liu, H.Y. Liu, H.Y. Lin, T.L. Hu, X.H. Bu, CrystEngComm. 10, 349 (2008)

    Article  CAS  Google Scholar 

  27. C. Volkringer, J. Marrot, G. Ferey, T. Loiseau, Cryst. Growth Des. 8, 685 (2008)

    Article  CAS  Google Scholar 

  28. X.R. Hao, X.L. Wang, Ch. Qin, Z.M. Su, E.B. Wang, Y.Q. Lan, K.S. Shao, Chem. Commun. 4620 (2007)

  29. L. Pan, H. Liu, S.P. Kelly, X. Huang, D.H. Olson, J. Li, Chem. Commun. 854 (2003)

  30. S.L. Zheng, M.L. Tong, X.L. Yu, X.M. Chen. J, Chem. Soc. Dalton. Trans. 586 (2001)

  31. L. Pan, N. Ching, X. Huang, J. Lee, J. Li, T. Yeun, C.L. Lin, J. Zan, Mat. Res. Soc. Sym. Proc. 848, 145 (2005)

    CAS  Google Scholar 

  32. J. Chen, Z. Chen, T. Yu, L. Weng, B. Tu, D. Zhao, Micropor. Mesopor. Mater. 98, 16 (2007)

    Article  CAS  Google Scholar 

  33. F.A.A. Paz, Y.Z. Khimyak, A.D. Bond, J. Rocha, J. Klinowski, Eur. J. Inorg. Chem. 2823 (2002)

  34. S.L. Zheng, M. L. Tong, X.L. Yu, X.M. Chen, J. Chem. Soc., Dalton Trans. 586 (2001)

  35. Q.R. Fang, G. S. Zhu, Z. Jin, M. Xue, X. Wei, P.J. Wang, S.L. Qiu, Cryst. Growth Des. 7, 1035 (2007)

    Article  CAS  Google Scholar 

  36. Y.F. Han, X.H. Zhou, Y.X. Zheng, Z. Shen, Y. Song, X.Z. You, CrystEngComm. 10, 1237 (2008)

    Article  CAS  Google Scholar 

  37. M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, O.M. Yaghi, Science 295, 469 (2002)

    Article  CAS  Google Scholar 

  38. A. Pichon, C.M. Fierro, M. Nieuwenhuyzen, S.L. James, CrystEngComm 9, 449 (2007)

    Article  CAS  Google Scholar 

  39. J.Y. Lee, L. Pan, S. P. Kelly, J. Jagiełło, T.J. Emge, J. Li, Adv. Mater. 17, 2703 (2005)

    Article  CAS  Google Scholar 

  40. N.L. Rosi, M. Eddaoudi, J. Kim, M. O’Keeffe, O.M. Yaghi, Angew. Chem. Int. Ed. 41, 284 (2002)

    Article  CAS  Google Scholar 

  41. N.L. Rosi, J. Kim, M. Eddaoudi, B. Chen, M. O’Keeffe, O.M. Yaghi. J, Am. Chem. Soc. 127, 1504 (2005)

    Article  CAS  Google Scholar 

  42. K.O. Kongshaug, H. Fjellvag, J. Solid State Chem. 177, 1852 (2004)

    Article  CAS  Google Scholar 

  43. Y. Wang, B. Bredenkotter, B. Rieger, D. Volkmer, Dalton Trans. 689 (2007)

  44. J.A. Rood, B.C. Noll, K.W. Henderson, Main Group Chem. 5, 21 (2006)

    Article  CAS  Google Scholar 

  45. H. Furukawa, J. Kim, N.W. Ockwig, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 130, 11650 (2006)

    Article  Google Scholar 

  46. S.M. Hawxwell, H. Adams, L. Brammer, Acta Cryst. B62, 808 (2006)

    CAS  Google Scholar 

  47. B.Q. Ma, K.L. Mulfort, J.T. Hupp, Inorg. Chem. 44, 4912 (2005)

    Article  CAS  Google Scholar 

  48. C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Ferey, Science 315, 1828 (2007)

    Article  CAS  Google Scholar 

  49. H.K. Liu, X.W. Peng, Ch.H. Lin, Acta Cryst. E65, m237 (2009)

    CAS  Google Scholar 

  50. X. Guo, G. Zhu, Q. Fang, M. Xue, G. Tian, J. Su, X. Li, S. Qiu, Inorg. Chem. 44, 3850 (2005)

    Article  CAS  Google Scholar 

  51. K.B. Shiu, H.Ch. Lee, G.H. Lee, B.T. Ko, Y. Wang, Ch.Ch. Lin, Angew. Chem. Int. Ed. 42, 2999 (2003)

    Article  CAS  Google Scholar 

  52. L.S. Long, Y.P. Ren, L.H. Ma, Y.B. Jiang, R.B. Huang, L.S. Zheng, Inorg. Chem. Commun. 6, 690 (2003)

    Article  CAS  Google Scholar 

  53. S.H. Cho, B. Ma, S.T. Nguyen, J.T. Hupp, T.E. Albrecht-Schmitt. Chem. Commun. 2563 (2006)

  54. L. Pan, H. Liu, X. Lei, X. Huang, D.H. Olson, N.J. Turro, J. Li, Angew. Chem., Int. Ed. 42, 542 (2003)

    Article  CAS  Google Scholar 

  55. F.A. Cotton, C.A. Murillo, S.E. Stiriba, X. Wang, R. Yu, Inorg. Chem. 44, 8223 (2005)

    Article  CAS  Google Scholar 

  56. S.H. Kim, H.S. Huh, S.W. Lee, J. Mol. Struct. 841, 78 (2007)

    Article  CAS  Google Scholar 

  57. J. Tao, X. Yin, R. Huang, L. Zheng, S.W. Ng, Inorg Chem. Commun. 5, 975 (2002)

    Article  CAS  Google Scholar 

  58. Q.R. Fang, X. Shi, G. Wu, G. Tian, G.S. Zhu, Y.F. Li, L.F. Wang, Ch.L. Wang, Y. Chen, Z.D. Zhang, Z. Guo, T.C. Shang, X.H. Cai, S.L. Qiu, Acta Chim. Sinica 60, 2087 (2002)

    CAS  Google Scholar 

  59. Q. Fang, X. Shi, G. Wu, G. Tian, G. Zhu, R. Wang, S. Qiu, J. Solid State Chem. 176, 1 (2003)

    Article  CAS  Google Scholar 

  60. S. Surble, C. Serre, C. Mellot-Draznieks, F. Millange, G. Ferey, Chem. Commun. 284 (2006)

  61. F. Luo, Y.. Che, J.M. Zheng, Cryst. Growth Des. 9, 1066 (2009)

    Article  CAS  Google Scholar 

  62. R.P. Davies, R.J. Less, P. Lickiss, A.J. P. White, Dalton. Trans. 2528 (2007)

  63. J. He, Y. Zhang, J. Yu, Q. Pan, R. Xi, Mater. Res. Bull. 41, 925 (2005)

    Article  Google Scholar 

  64. R.D. Poulsen, J. Overgaard, M.-A. Chevallier, H.F. Clausen, B.B. Iversen, Acta Cryst. E61, m2308 (2005)

    CAS  Google Scholar 

  65. L. Pan, B.S. Finkel, X. Huang. J. Li, Chem. Commun. 105 (2001)

  66. P.Q. Zheng, L.S. Long, R.B. Huang, L.S. Zheng, Main Group Met. Chem. 25, 701 (2002)

    Article  CAS  Google Scholar 

  67. Q.R. Fang, G.S. Zhu, Z. Jin, Y.Y. Ji, J.W. Ye, M. Xue, H. Yang, Y. Wang, S.L. Qiu, Angew. Chem. Int. Ed. 46, 6638 (2007)

    Article  CAS  Google Scholar 

  68. R. Łyszczek, Thermochim. Acta 509, 120 (2010)

    Article  Google Scholar 

  69. R. Łyszczek, J. Therm. Anal. Cal. 90, 533 (2007)

    Article  Google Scholar 

  70. R. Łyszczek, J. Therm. Anal. Cal. 93, 833 (2008)

    Article  Google Scholar 

  71. R. Łyszczek, J. Anal. Appl. Pyrolysis 86, 239 (2009)

    Article  Google Scholar 

  72. R. Łyszczek, Appl. Surf. Sci. 257(5), 1736 (2010)

    Article  Google Scholar 

  73. Oxford Diffraction, Xcalibur CCD System, CrysAlis Software System, Version 1.171 (Oxford Diffraction Ltd., Oxford, 2009)

    Google Scholar 

  74. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    CAS  Google Scholar 

  75. H.Y. Lin, X.L. Wang, H.L. Hu, B.K. Chen, G.C. Liu, Solid State Sci. 11, 643 (2009)

    Article  CAS  Google Scholar 

  76. S.Y. Zhang, M.X. Yu, L.G. Zhu, J. Mol. Struc. 699, 101 (2004)

    Article  CAS  Google Scholar 

  77. G. Durgaprasad, D.N. Sathyanarayana, C.C. Patet, Bulletin Chem. Soc. Jap. 44 316 (1971)

    Article  CAS  Google Scholar 

  78. A. Sharma, S. Kaur, C. G. Mahajan, S. K. Tripathi, G.S.S. Saini, Mol. Phys. 105, 117 (2007)

    Article  CAS  Google Scholar 

  79. T.C. Jao, I. Scott, D. Steele, Journal of Molecular Spectroscopy 92, 1 (1982)

    Article  CAS  Google Scholar 

  80. S. Holly, P. Soha, Absorption Spectra in the Infrared Region (Akademiai Kiado, Budapest, 1975)

    Google Scholar 

  81. R.M. Silverstein, F.X. Webster, Spectrometric Identification of Organic Compounds, 6th edition (JohnWiley&Sons, New York, 1998)

    Google Scholar 

  82. A. Mech, Polyhedron 27 (2008) 393

    Article  CAS  Google Scholar 

  83. I. Georgiewa, N. Trendafilova, W. Kiefer, V.K. Rastogi, I. Kostova, Vibrational Spectroscopy 44, 78 (2007)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska Univeristy, 20-031, Lublin, Poland

    Renata Łyszczek & Liliana Mazur

Authors
  1. Renata Łyszczek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Liliana Mazur
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Renata Łyszczek.

Electronic supplementary material

About this article

Cite this article

Łyszczek, R., Mazur, L. Synthesis, crystal structure, spectroscopic and thermal investigations of neodymium(III) biphenyl-4,4′-dicarboxylate framework. cent.eur.j.chem. 10, 1165–1174 (2012). https://doi.org/10.2478/s11532-012-0035-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s11532-012-0035-0

Keywords

Search

Navigation