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Structure-reactivity relationships in organosilicon chemistry revisited

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Central European Journal of Chemistry

Abstract

Available quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative to the carbon chemistry values, the scale of steric constants E S (Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects, steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis can be employed in investigations of organosilicon reactions along with other methods.

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Authors and Affiliations

  1. Institute of Chemistry, University of Tartu, Tartu, 50411, Estonia

    Anu Ploom, Ants Tuulmets & Jaak Järv

  2. Department of Chemistry, Faculty of Science, Tallinn University of Technology, Tallinn, 12618, Estonia

    Anu Ploom

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  1. Anu Ploom
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  2. Ants Tuulmets
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  3. Jaak Järv
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Correspondence to Anu Ploom.

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Ploom, A., Tuulmets, A. & Järv, J. Structure-reactivity relationships in organosilicon chemistry revisited. cent.eur.j.chem. 9, 910–916 (2011). https://doi.org/10.2478/s11532-011-0075-x

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  • DOI: https://doi.org/10.2478/s11532-011-0075-x

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