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Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration

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Central European Journal of Chemistry

Abstract

A new amperometric titration method was developed for quantitative determination of ferrate(VI) (FeVIO4 2−) in the 7.06×10−5−5.73×10−3 M concentration range. Chromium(III) hydroxide solution was used as the titrant. The diffusion current (Id) had a linear relationship with the concentration of ferrate(VI) and slopes were dependent on the concentration of NaOH. The amperometric titration could detect a lower concentration of ferrate(VI) than could potentiometric and colorimetric titrations. The method was applied successfully to determine concentrations of ferrate(VI), generated electrochemically, in strong alkaline solutions.

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Authors and Affiliations

  1. Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine

    Dmitriy A. Golovko, Olga. V. Pavlova, Elena. A. Belyanovskaya, Igor. D. Golovko & Victoria. I. Suprunovich

  2. Chemistry Department, Florida Institute of Technology, Melbourne, Florida, 32901, USA

    Virender K. Sharma

  3. Nanomaterial Research Centre, Palacky University, 771 46, Olomouc, Czech Republic

    Radek Zboril

Authors
  1. Dmitriy A. Golovko
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  2. Virender K. Sharma
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  3. Olga. V. Pavlova
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  4. Elena. A. Belyanovskaya
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  5. Igor. D. Golovko
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  6. Victoria. I. Suprunovich
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  7. Radek Zboril
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Correspondence to Virender K. Sharma.

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Golovko, D.A., Sharma, V.K., Pavlova, O.V. et al. Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration. cent.eur.j.chem. 9, 808–812 (2011). https://doi.org/10.2478/s11532-011-0069-8

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  • DOI: https://doi.org/10.2478/s11532-011-0069-8

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