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Analysis of crystallographic and structural data of polymeric FeM (M = transition metals, lanthanides) complexes

  • Review Article
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Central European Journal of Chemistry

Abstract

This review covers crystallographic and structural data for almost fifty polymeric FeM complexes (M = transition Cu, Ag, Au, Mo, W, Mn, Co, Ni and Pt and lanthanide elements Sm, Er and Yb) where iron is involved in polymeric chains. The complexes are for the most part yellow or black, but there are complexes of brown, orange, red, purple, blue and green colour. The complexes crystallized in the monoclinic (by far prevails), triclinic, tetragonal, orthorhombic, trigonal, hexagonal and rhombohedral crystal classes. The iron atoms are found in oxidation states 0, +2 and +3, of which +3 by far prevails. The inner coordination spheres about the Fe(0) atom are tetrahedral (FeC4) or sandwiched (FeC10), Fe(II) atoms are six-coordinated, and Fe(III) are six or even seven-coordinated. The inner coordination about M atoms range from four- through six- to eight-coordinated. The shortest Fe-Fe, Fe-M (transition) and Fe-M (lanthanide) and M-M separations are: 8.08 Å, 3.033 Å for Fe-Cu, 3.010 Å for Fe-Yb and 2.505 Å for Mo-Mo.

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References

  1. M. Melník, Z. Baloghová, I. Ondrejkovičová, V. Vančová, C.E. Holloway, Rev. Inorg. Chem. 26, 1 (2006)

    Article  Google Scholar 

  2. M. Melník, I. Ondrejkovičová, D. Mikloš, P. Segl’a, C.E. Holloway, Rev. Inorg. Chem. 27, 67 (2007)

    Article  Google Scholar 

  3. M. Melník, I. Ondrejkovičová, M. Sundberg, C.E. Holloway, Rev. Inorg. Chem. 28, 237 (2008)

    Article  Google Scholar 

  4. M. Melník, I. Ondrejkovičová, M. Koman, C.E. Holloway, Rev. Inorg. Chem. 30, 1 (2010)

    Article  Google Scholar 

  5. M. Melnik, C.E. Holloway, Rev. Inorg. Chem. (in press)

  6. M. Melník, J. Garaj, C.E. Holloway, In: A.G. Mirsky (Ed.), Thermochemistry and Advances in Chemistry Research (Nova Sc. Publ. Inc., New York, 2009) chapter 8, pp. 217–250

    Google Scholar 

  7. M. Melník, M. Sundberg, R. Uggla, Main Group Met. Chem. (in press)

  8. M. Melník, M. Sundberg, R. Uggla, Main Group Met. Chem. (in press)

  9. G.O. Morpurgo, V. Morini, P. Porta, G. Dessy, V. Faras, J. Chem. Soc., Dalton Trans. 1272 (1980)

  10. G.O. Morpugo, V. Morini, P. Porta, G. Bessy, V. Faras, J. Chem. Soc., Dalton Trans. 111 (1981)

  11. H. Zhong, D.-Zh. Liao, P. Cheng, Z.-H. Jiong, S.-P. Yan, G.-L. Wang, X.-K. Yao, H.-G. Wang, J. Chem. Soc., Dalton Trans. 1503 (1997)

  12. T. Kaufmann, B. Shamsai, R.S. Lee, R. Ban, G.M. Miskelly, Inorg. Chem. 34, 5073 (1995)

    Article  CAS  Google Scholar 

  13. Morgenstan-Baradau, D. Laroque, E. Bill, H. Winkler, A.X. Trautwein, F. Robert, Y. Jannin, Inorg. Chem. 30, 3180 (1991)

    Article  Google Scholar 

  14. P. Gomez-Romero, G.B. Jameson, J.J. Bornas-Almenar, E. Escriva, E. Coronado, D. Belron, J. Chem. Soc., Dalton Trans. 2747 (1988)

  15. L.R. Masinboni, M.M. Thacheray, Acta Crystallog., Sec. B 30, 1072 (1974)

    Article  Google Scholar 

  16. X. Solans, M.F. Abtaba, J. Garcia-Oricain, Acta Crystallogr., Sec. C40, 635 (1984)

    Article  CAS  Google Scholar 

  17. O. Crespo, M.C. Gimeno, D.G. Jones, A. Laguna, C. Sarroca, J. Chem. Soc., Chem. Commun. 1481 (1998)

  18. M.C. Gimeno, P.G. Jones, A. Laguna, G. Sarroca, J. Chem. Soc., Dalton Trans. 1277 (1998)

  19. A. Houlton, D.M.P. Mingos, D.M. Murphy, D.J. Wiliams, L.-T. Phang, T.S.A. Hor, J. Chem. Soc. Dalton Trans. 3629 (1993)

  20. L.-T. Phang, T.S. Andy Hor, Zh.-Y. Zhou, T.C.V. Mak, J. Organomet. Chem. 469, 253 (1994)

    Article  CAS  Google Scholar 

  21. H. Liu, L. Xu, J. Huang, W. Chen, Q. Zhang, Acta Crystallogr., Sect. C 52, 69 (1996)

    Article  Google Scholar 

  22. L. Xu, Zh. Li, Huang, H. Liu, J. Huang, Q. Zhang, Chem. Eur. J. 3, 226 (1997)

    Article  CAS  Google Scholar 

  23. L.A. Meyer, R. Haushalter, Inorg. Chem. 32, 1579 (1993)

    Article  CAS  Google Scholar 

  24. D.I. Mulica, D.B. Tippin, E.L. Sapenfield, Inorg. Chim. Acta. 174, 129 (1990)

    Article  Google Scholar 

  25. H. Henkel, D. Babel, Z. Naturforsch. 39B, 880 (1984)

    CAS  Google Scholar 

  26. N. Re, E. Gallo, C. Floriani, H. Miyasaka, N. Matsumoto, Inorg. Chem. 35, 6004 (1996)

    Article  CAS  Google Scholar 

  27. H. Miyasaka, N. Matsumoto, H. Okawa, N. Ra, E. Galld, C. Floriani, J. Amer. Chem. Soc. 118, 981 (1996)

    Article  CAS  Google Scholar 

  28. R. Peleux, H.W. Schmalc, R. Huber, P. Fischer, T. Hauss, B Ouladdiaf, S. Decurtins, Inorg. Chem. 36, 2301 (1997)

    Article  Google Scholar 

  29. S.G. Carling, C. Mathoniere, P. Day, K.M Abdul Malik, S.J. Coles, M.B. Hursthouse, J. Chem. Soc., Dalton Trans. 1839 (1996)

  30. M. Clemente-León, E. Coronado, J.R. Galán-Mascarós, C.J. Gómer-Garciá, Chem. Commun. 1727 (1997)

  31. H. Furutachi, H. Okawa, Inorg. Chem. 36, 3911 (1997)

    Article  CAS  Google Scholar 

  32. M. Ohba, N. Usuki, N. Fukita, H. Okawa, Inorg. Chem. 37, 3349 (1998)

    Article  CAS  Google Scholar 

  33. T. Kitazawa, N. Furunaga, M. Takahashi, M. Takeda, Mol. Cryst. Sci. Technol., Sect A 244, 331 (1994)

    Article  CAS  Google Scholar 

  34. H. Yuge, C.H. Kim, T. Iwamoto, T. Kitazawa, Inorg. Chim. Acta 257, 217 (1997)

    Article  CAS  Google Scholar 

  35. T. Nakano, T. Miyoshi, T. Iwamoto, Y. Sasaki, Bull. Chem. Soc. Japan 40, 1297 (1967)

    Article  CAS  Google Scholar 

  36. T. Kitazawa, Y. Gomi, M. Takahashi, M. Takeda, M. Enomoto, A. Miyzaki, T. Enoki, J. Mater. Chem. 6, 119 (1996)

    Article  CAS  Google Scholar 

  37. M. Ohba, H. Okawa, N. Fukita, Y. Hashimoto, J. Amer. Chem. Soc. 119, 1011 (1997)

    Article  CAS  Google Scholar 

  38. N. Fukita, M. Ohba, H. Okawa, K. Matsuda, H. Iwamura, Inorg. Chem. 37, 842 (1998)

    Article  CAS  Google Scholar 

  39. J.S. Miller, J.C. Calabrese, A.J. Epstain, Inorg. Chem. 28, 4230 (1989)

    Article  CAS  Google Scholar 

  40. V. Krasnikov, M. Vaivada, Z. Konstants, J. Solid State Chem. 74, 9 (1988)

    Article  Google Scholar 

  41. S. Dommann, H. Vetsch, F. Hulliger, W. Petter, Acta Crystalogr., Sect. C 46, 1992 (1990)

    Article  Google Scholar 

  42. H. Deng, S.G. Shore, J. Amer. Chem. Soc. 113, 8538 (1991)

    Article  CAS  Google Scholar 

  43. H. Deng, S.-H. Chum, P. Florian, P.J. Grandinetti, S.G. Shore, Inorg. Chem. 35, 3891 (1996)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Slovak Technical University, Radlinskeho 9, 812 37, Bratislava, Slovak Republic

    Milan Melnik & Ján Garaj

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  1. Milan Melnik
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  2. Ján Garaj
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Correspondence to Milan Melnik.

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Melnik, M., Garaj, J. Analysis of crystallographic and structural data of polymeric FeM (M = transition metals, lanthanides) complexes. cent.eur.j.chem. 9, 776–789 (2011). https://doi.org/10.2478/s11532-011-0067-x

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  • DOI: https://doi.org/10.2478/s11532-011-0067-x

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