Skip to main content
SpringerLink
Log in

Alkaline hydrolysis of brilliant green in mixed cationic surfactant systems

  • Research Article
  • Published:
Central European Journal of Chemistry

Abstract

Kinetic measurements were performed for the alkaline hydrolysis of brilliant green — a triphenylmethane dye used as a model compound for probing micellar rate effects. This reaction was studied both in the presence of tetradecyltrimethylammonium bromide (TTAB) and tetradecyltriphenylphosphonium bromide (TTPPBr) and also in binary mixtures of these surfactants at different mole fractions of each. All rate surfactant profiles were analyzed using the pseudo-phase model in order to obtain the regression parameters, including binding constants and rate constants in the micellar pseudo-phase. The reaction was catalyzed by both surfactants. The catalytic factor increases from about 10 for pure TTPPBr to about 38 for pure TTAB. Binding of BG to micellar surface is greater in pure TTAB than in pure TTPPBr but significantly reduced in the surfactant mixtures than in pure components. Reduction of the binding constant becomes more significant as the mole fraction of TTAB is increased in the mixture. The kinetic data have been analyzed in terms of models of Piszkiewicz and Raghavan-Srinivasan which are in good agreement.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Ogino, M. Abe (Eds.), Mixed Surfactant Systems (Dekker, New York, 1993)

    Google Scholar 

  2. M. El-Batanoney, T. Abdel-Moghny, M. Ramzi, J. Surf. Det. 2, 201 (1999)

    Article  CAS  Google Scholar 

  3. M.J. Rosen, H. Wang, P. Shen, Y. Zhu, Langmuir 2, 3749 (2005)

    Article  Google Scholar 

  4. A.E. Kharlov. G.P. Yampol’skaya, Moscow Univ. Chem. Bull. 62, 22 (2007)

    Google Scholar 

  5. F.T. Tadros, Applied Surfactants (Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim, 2005)

    Book  Google Scholar 

  6. T.J. Hall-Manning, G.H. Holland, G. Rennie, P. Revell, J. Hines, M.D. Barret, D.A. Basketter, Food Chem. Toxic. 36, 233 (1998)

    Article  CAS  Google Scholar 

  7. Y. Yu, Z. Jin, A.E. Bayly, Chin. J. Chem. Eng. 16, 517 (2008)

    Article  CAS  Google Scholar 

  8. T. Satsuki, Y. Nagoh, H. Yoshimura, J. Jap. Oil Chemist Soc. 48, 109 (1999)

    CAS  Google Scholar 

  9. J.L. Parra, J.J. Garcia-Dominuguez, A. de la Maza, J.S. Leal, J. Soc. Dyers Colourists 102, 227 (2008)

    Article  Google Scholar 

  10. R.J. Goetz, M. El-Aasser, Langmuir 17, 993 (1990)

    Google Scholar 

  11. H. Hoffmann, G. Poessnecker, Langmuir 10, 381 (1994)

    Article  CAS  Google Scholar 

  12. E. Marques, K. Khan, M. de-Miguel, B. Lindman, J. Phys. Chem. 97, 4729 (1993)

    Article  CAS  Google Scholar 

  13. T. P. Goloub, R.J. Pugh, B.V. Zhmud, J. Colloid Interface Sci. 229, 72 (2000)

    Article  CAS  Google Scholar 

  14. M. Bergstrom, Langmuir 17, 993 (2001)

    Article  Google Scholar 

  15. M. Munoz, M. Rodriguez, M. D. Graciani, M.L. Moya, Int. J. Chem. Kinet. 34, 445 (2002)

    Article  CAS  Google Scholar 

  16. M.N. Khan, E. Ismail, M.R. Yussof, J. Phys. Org. Chem. 14, 669 (2001)

    Article  CAS  Google Scholar 

  17. G. Fernandez, A. Rodriguez, M. D. Graciani, M. Munoz, M.L. Moya, Int. J. Chem. Kinet. 35, 45 (2003)

    Article  CAS  Google Scholar 

  18. H.M. Joshi, T.N. Nagar, Asian J. Chem. 14, 1763 (2002)

    CAS  Google Scholar 

  19. K.K. Ghosh, A. Pandey, J. Indian Chem. Soc. 76, 191 (1999)

    CAS  Google Scholar 

  20. R. Bacaloglu, A. Blasko, C.A. Bunton, G. Cerichelli, F. Ortega, J. Phys. Chem. 94, 5062 (1990)

    Article  Google Scholar 

  21. R. Bacaloglu, C.A. Bunton, G. Cerichelli, F. Ortega, J. Phys. Chem. 94, 5068 (1990)

    Article  CAS  Google Scholar 

  22. M.M. Mohareb, K.K. Ghosh, G. Orlova, R.M. Palepu, J. Phys. Org. Chem. 19, 281 (2006)

    Article  CAS  Google Scholar 

  23. D.F. Duxbury, Chem. Rev. 93, 381 (1993)

    Article  CAS  Google Scholar 

  24. B.M. Fox, G. Hallas, J.D. Hepworth, D. Mason, J. Chem. Tech. Biotech. 30, 317 (1980)

    CAS  Google Scholar 

  25. B.M. Fox, J.D. Hepworth, D. Mason, G. Hallas, J. Chem. Soc. (Perkin Trans. 2), 8, 987 (1982)

    Article  Google Scholar 

  26. J.D. Hepworth, D.J. Lythgoe, D. Mason, G. Hallas, Dyes Pigments 15, 31 (1991)

    Article  CAS  Google Scholar 

  27. O. Owoyomi, J. Ige, O. Soriyan, G. Ogunlusi, S.E. Olaseni, O. Olanrewaju, Acta Chim. Slov. 54, 370 (2007)

    Google Scholar 

  28. D.J. Jobe, V.C. Reinsborough, Aust. J. Chem. 37, 1593 (1984)

    Article  CAS  Google Scholar 

  29. D. Piszkiewicz, J. Amer. Chem. Soc. 99, 1550 (1977)

    Article  CAS  Google Scholar 

  30. A.V. Hill, J. Physiol. (London) 40, 4 (1910)

    Google Scholar 

  31. E. Pandey, S.K. Uphaday, Colloids Surf. A: Physicochem. Eng. Aspects 269, 7 (2005)

    Article  CAS  Google Scholar 

  32. C.E. Drennan, R.J. Hughes, V.C. Reinsborough, O.O. Soriyan, Can. J. Chem. 76, 152 (1998)

    Article  CAS  Google Scholar 

  33. P.S. Raghavan, V.S. Srinavasan, Proc. Indian Acad. Sci. (Chem. Sci.) 98, 199 (1987)

    Article  CAS  Google Scholar 

  34. L.S. Romsted, In K.L. Mittal (Ed.), Micellization, Solubilization and Microemulsions (Plenum Press, New York, 1977) 2, 509

    Google Scholar 

  35. R.L. Reeves, J. Amer. Chem. Soc. 97, 6019 (1975)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science Obafemi Awolowo University, Ile Ife, 220005, Nigeria

    Owoyomi Olanrewaju, Jide Ige & Soriyan O. Omopariola

Authors
  1. Owoyomi Olanrewaju
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jide Ige
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Soriyan O. Omopariola
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Owoyomi Olanrewaju.

About this article

Cite this article

Olanrewaju, O., Ige, J. & Omopariola, S.O. Alkaline hydrolysis of brilliant green in mixed cationic surfactant systems. cent.eur.j.chem. 9, 106–111 (2011). https://doi.org/10.2478/s11532-010-0120-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s11532-010-0120-1

Keywords

Search

Navigation