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Ionic liquids - deanol derivatives as the Diels-Alder reaction solvents

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Central European Journal of Chemistry

Abstract

The Diels-Alder reaction between cyclopentadiene and dienophiles in deanol derivatives containing bis(trifluoromethylsulfonyl)imide anion as media have been studied. The effect of the substituents attached to the cation on the endo:exo selectivity as well as the reaction yield have been evaluated in the absence and presence of Lewis acid catalyst - Y(OTf)3. Catalytic activity of metal triflates and the recycling of chosen catalytic systems have also been investigated

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Authors and Affiliations

  1. Department of Organic Chemical Technology, West Pomeranian University of Technology, 70-322, Szczecin, Poland

    Ewa Janus

  2. Department of Chemical Technology, Poznan University of Technology, 60-965, Poznań, Poland

    Anna Syguda & Katarzyna Materna

Authors
  1. Ewa Janus
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  2. Anna Syguda
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  3. Katarzyna Materna
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Correspondence to Katarzyna Materna.

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Janus, E., Syguda, A. & Materna, K. Ionic liquids - deanol derivatives as the Diels-Alder reaction solvents. cent.eur.j.chem. 8, 1140–1146 (2010). https://doi.org/10.2478/s11532-010-0092-1

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  • DOI: https://doi.org/10.2478/s11532-010-0092-1

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