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Synthesis, characterization, catalytic and antimicrobial studies of ruthenium(III) complexes

Central European Journal of Chemistry volume 8, pages 842–851 (2010)Cite this article

Abstract

Ru(III) complexes of the type [RuXB(L)2] have been prepared by the reaction of 3,4-dihydropyrimidin-2(1H)-ones/thiones (HL1–HL4) with the precursors of the type [RuX3B3] where X=Cl or Br; B=PPh3 or AsPh3 and L is the deprotonated ligand. The synthesized complexes were characterized by physico-chemical methods, electrochemical and magnetic moment data. The catalytic efficiency of the complexes were examined in the oxidation of alcohols and antimicrobial studies were also carried out.

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References

  1. B.R. Sarkar, R.V. Chaudhari, Catal. Surv. Asia 9, 3 (2005)

    Article  Google Scholar 

  2. S.I. Murahashi, D. Zhang, Chem. Soc. Rev. 37, 1490 (2008)

    Article  CAS  Google Scholar 

  3. D. Bagchi, S.J. Stohs, B.W. Downs, M. Bagchi, H.G. Preuss, Toxicology 180, 5 (2002)

    Article  CAS  Google Scholar 

  4. I.M. Geraskin, M.W. Luedtke, H.M. Neu, V.N Nemykin, V.V. Zhdankin, Tetrahedron Lett. 49, 7410 (2008)

    Article  CAS  Google Scholar 

  5. M. Picqueta et al., Top. Catal. 29, 3 (2004)

    Article  Google Scholar 

  6. M. Rong, C. Liu, J. Han, H. Wang, Catal. Commun. 10, 362 (2009)

    Article  CAS  Google Scholar 

  7. A.K. Singh, N. Chaurasia, S. Rahmani, J. Srivastava, B. Singh, Catal. Lett. 95, 3 (2004)

    Article  Google Scholar 

  8. F. Adam, I.A. Sugiarmawan, J. Porous Mater. 16, DOI:10.1007/s10934-008-9203-1(2009)

  9. D. Subhas Bose, M. Sudharshan, S.W. Chavhan, Arkivoc 3, 228 (2005)

    Google Scholar 

  10. R. Hekmatshoar, M. Heidari, M.M. Heravi, B. Baghernejad, J. Korean Chem. Soc. 53, 90 (2009)

    CAS  Google Scholar 

  11. J.A. Garcia-Vazquez, J. Romero, A. Sousa-Pedrares, M.L. Louro, A. Sousa, J. Zubieta, J. Chem. Soc. Dalton Trans. 559 (2000)

  12. N. Thilagavathi, A. Manimaran, N. Padmapriya, N. Sathya, C. Jayabalakrishnan, Trans. Met. Chem. 34, 725 (2009)

    Article  CAS  Google Scholar 

  13. A.I. Vogel, Text book of practical organic chemistry, 5th edition (Longmann, London, 1989)

    Google Scholar 

  14. J. Chatt, G. Leigh, D.M.P. Mingos, R.J. Paske, J. Chem. Soc. A 2636 (1968)

  15. P. Viswanathamurthi, K. Natarajan, Indian J. Chem. 38, 797 (1999)

    Google Scholar 

  16. K. Natarajan, R.K. Poddar, U. Agarwala, J. Inorg. Nucl. Chem. 39, 431(1977)

    Article  CAS  Google Scholar 

  17. B. Gangadasu, P. Narender, B. China Raju, V. Jayathirtha Rao, Indian J. Chem. A 45, 1259 (2006)

    Google Scholar 

  18. C. Jayabalakrishnan, R. Karvembu, K. Natarajan, Trans. Met. Chem. 27, 790 (2002)

    Article  CAS  Google Scholar 

  19. G. Asgedom, A. Sreedhara, J. Kivikoshi, C.P. Rao, Polyhedron 16, 643 (1997)

    Article  CAS  Google Scholar 

  20. C.H. Collins, P.M. Lyne, Microbial Methods (University Park Press, Baltimore, 1970)

    Google Scholar 

  21. S.I. Mostafa, N. Hadjiliadis, Trans. Met. Chem. 33, 529 (2008)

    Article  CAS  Google Scholar 

  22. A.Z. El-Sonbati, A.A. El-Bindary, A. El-Dssouky, T.M. El-Gogary, A.S. Hilali, Spectrochim. Acta A 58, 1623 (2002)

    Article  CAS  Google Scholar 

  23. V.K. Sharma, S. Srivatsava, A. Srivatsava, Bioinorg. Chem. Appl., doi:10.1155/2007/68374 (2007)

  24. M.M. Taqui Khan, V. Vijay Sen Reddy, Inorg. Chem. 25, 208 (1986)

    Article  Google Scholar 

  25. M. Adib, K. Ghanbary, M. Mostofi, M. Reza Ganjali, Molecules, 11, 649 (2006)

    Article  CAS  Google Scholar 

  26. F.S. Falsone, C. Oliver Kappe, Arkivoc, 122 (2001)

  27. M.S. Masoud, E.A. Khalil, A.M. Ramadan, Y.M. Gohar, A. Sweyllam, Spectrochim. Acta A 67, 669 (2007)

    Article  Google Scholar 

  28. A. Z. El-Sonbati, A.A. El-Bindary, A.F. Shoair, Spectrochim. Acta 58, 3003 (2002)

    Article  CAS  Google Scholar 

  29. R. Raveendran, S. Pal, J. Organomet. Chem. 692, 824 (2007)

    Article  CAS  Google Scholar 

  30. T. Hashimoto, S. Hara, Y. Shiraishi, M. Yamauchi, K. Natarajan, K. Shimizu, Inorg. Chim. Acta 358, 2207 (2005)

    Article  CAS  Google Scholar 

  31. K. Vijayasri, J. Rajaram, J.C. Kuriacose, J. Mol. Catal. 39, 203 (1987)

    Article  CAS  Google Scholar 

  32. M. Hasan, M. Musawir, P.N. Davey, I.V. Kozhevnikov, J. Mol. Catal. A Chem. 180, 77 (2002)

    Article  CAS  Google Scholar 

  33. P.K. Bhattacharya, Proc. Indian Acad. Sci. (Chem. Sci.) 102, 247 (1990)

    CAS  Google Scholar 

  34. P. Paraskevopoulou, N. Psaroudakis, S. Koinis, P. Stavropoulos, K. Mertis, J. Mol. Catal. Chem. 240, 27 (2005)

    CAS  Google Scholar 

  35. M.V. Kaveri, R. Prabhakaran, R. Karvembu, K. Natarajan, Spectrochim. Acta A 61, 2915 (2005)

    Article  CAS  Google Scholar 

  36. S. Chandra, S. Raizada, M. Tyagi, A. Gautham, Bioinorg. Chem. Appl., doi: 10.1155 / 2007 / 51483 (2007)

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Authors and Affiliations

  1. Department of Chemistry, Surya Engineering College, Erode-638 107, Tamil Nadu, India

    Natarajan Thilagavathi

  2. Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641 020, Tamil Nadu, India

    Chinnasamy Jayabalakrishnan

Authors
  1. Natarajan Thilagavathi
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  2. Chinnasamy Jayabalakrishnan
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Correspondence to Chinnasamy Jayabalakrishnan.

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Thilagavathi, N., Jayabalakrishnan, C. Synthesis, characterization, catalytic and antimicrobial studies of ruthenium(III) complexes. cent.eur.j.chem. 8, 842–851 (2010). https://doi.org/10.2478/s11532-010-0045-8

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  • DOI: https://doi.org/10.2478/s11532-010-0045-8

Keywords

  • Ruthenium(III)
  • NMO
  • Antimicrobial activity
  • EPR
  • Cyclic voltammetry