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Surfactant to dye binding degree method for the determination of fluvoxamine maleate and citalopram hydrobromide in pharmaceuticals

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Central European Journal of Chemistry

Abstract

The surfactant to dye binding degree (SBDB) methodology was used to determine fluvoxamine maleate and citalopram hydrobromide. Neutral red and sodium dodecyl sulfate (SDS) were used as the dye and surfactant, respectively, to form dye-surfactant aggregates. When a cationic drug is added to dye-surfactant mixture, it interacts with the surfactant and decreases the dye-surfactant binding degree. This decrease is proportional to the drug concentration. This was measured by monitoring the absorbance changes of the dye at 532 nm. Under the optimum conditions, the calibration graphs were linear over the range of 1.2–15 μg mL−1 and 1.1–15 μg mL−1 for fluvoxamine maleate and citalopram hydrobromide, respectively. The detection limits (signal to noise ratio = 3) were found to be 0.37 and 0.35 μg mL−1, for fluvoxamine maleate and citalopram hydrobromide, respectively.

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References

  1. W.Z. Potter, L.E. Hollister, In: B. Katzung (Ed.), Basic & Clinical Pharmacology, 9th edition (McGraw-Hill Companies, USA, 2004) 482

    Google Scholar 

  2. J. Menegola, M. Steppe, E.E.S. Schapoval, J. AOAC Int. 91, 52 (2008)

    CAS  Google Scholar 

  3. A. Raza, Chem. Pharm. Bull. 54, 432 (2006)

    Article  CAS  Google Scholar 

  4. A.A. Alhaider, M.E.M. Hagga, M.E. Alawady, E.A. Gadkariem, Anal. Lett. 26, 887 (1993)

    CAS  Google Scholar 

  5. B. Starczewska, K. Mielech, J. Pharm. Biomed. Anal. 23, 243 (2000)

    Article  CAS  Google Scholar 

  6. I.A. Darwish, H.H. Abdine, S.M. Amer, L.I. Al-Rayes, Spectrochim. Acta, Part A. 72, 894 (2009)

    Google Scholar 

  7. Q.M. Li, J. Li, Z.J. Yang, Anal. Chim. Acta 583, 147 (2007)

    Article  CAS  Google Scholar 

  8. B. Starczewska, H. Puzanowska-Tarasiewicz, K. Baranowska, J. Pharm. Biomed. Anal. 23, 477 (2000)

    Article  CAS  Google Scholar 

  9. D.T. El-Sherbiny, J. AOAC Int. 89, 1288 (2006)

    CAS  Google Scholar 

  10. I.A. Darwish, S.M. Amer, H.H. Abdine, L.I. Al-Rayes, J. Fluoresc. 19, 463 (2009)

    Article  CAS  Google Scholar 

  11. S.G. Vasantharaju, S. Lakshmana Prabu, A. Jacob, Indian J. Pharmaceut. Sci. 70, 647 (2008)

    Article  Google Scholar 

  12. E. Şatana, N. Ertaş, N.G. Göğer, Chromatographia 66, 75 (2007)

    Google Scholar 

  13. S. Tatar Ulu, Chromatographia 64, 169 (2006)

    Article  Google Scholar 

  14. J. Menegola, M. Steppe, E.E.S. Schapoval, J. AOAC Int. 91, 52 (2008)

    CAS  Google Scholar 

  15. E. Şatana, Ü. Dilek Uysal, N. Göğer, M. Tunçel, Chromatographia 24, 317 (2006)

    Google Scholar 

  16. J.J. Berzas, A.M. Contento, M.J. Villaseñor, E. Aguas, Anal. Chim. Acta 417, 169 (2000)

    Article  Google Scholar 

  17. J.J. Berzas, M.J. Villaseñor, C. Guiberteau, V. Rodriguez, S. Buitrago, J. Sep. Sci. 29, 103 (2006)

    Article  Google Scholar 

  18. J.J. Berzas, M.J. Villaseñor, A.M. Contento, E. Agua, J. Pharm. Biomed. Anal. 38, 52 (2005)

    Google Scholar 

  19. J.J. Berzas, M.J. Villaseñor, A.M. Contento, E. Agua, J. Chromatogr. Sci. 38, 200 (2000)

    Google Scholar 

  20. T. Gondová, D. Halamová, K. Špacayová, J. Liq. Chromatogr. Related Technol. 31, 2429 (2008)

    Article  Google Scholar 

  21. H.P.A. Nouws, C. Delerue-Matos, A.A. Barros, Anal. Lett. 39, 1907 (2006)

    Article  Google Scholar 

  22. M. Tuncel, G. Altiokka, Z. Atkosar, Anal. Lett. 27, 1135 (1994)

    CAS  Google Scholar 

  23. J.J. Berzas, N.J. Rodriguez, G. Casteneda, Electroanalysis 12, 1059 (2000)

    Article  Google Scholar 

  24. H.P. Nouws, C. Delerue-Matos, A.A. Barros, J.A. Rodrigues, A. Santos-Silva, Anal. Bioanal. Chem. 382, 1662 (2005)

    Article  CAS  Google Scholar 

  25. H. Nouws, C. Delerue-Matos, A. Barros, Anal. Lett. 39, 1907 (2006)

    Article  Google Scholar 

  26. S. Schreier, S.V.P. Malheiros de Paula, Biochim. Biophys. Acta 23, 210 (2000)

    Google Scholar 

  27. Kabir-ud-Din, M.D.A. Al-Ahmadi, A.Z. Naqvi, M. Akram, Colloids Surf. B. 15, 65 (2008)

    Article  Google Scholar 

  28. R. Fabios, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Chem. 75, 6011 (2003)

    Article  CAS  Google Scholar 

  29. E.M. Costi, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Chim. Acta 577, 257 (2006)

    Article  CAS  Google Scholar 

  30. A. Pedraza, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Chim. Acta 588, 252 (2007)

    Article  CAS  Google Scholar 

  31. A. Pedraza, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Chim. Acta 522, 89 (2004)

    Article  CAS  Google Scholar 

  32. A. Pedraza, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Analyst 130, 1102 (2005)

    Article  CAS  Google Scholar 

  33. A. Pedraza, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Analyst 131, 81 (2006)

    Article  CAS  Google Scholar 

  34. E.M. Costi, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Chim. Acta 549, 159 (2005)

    Article  CAS  Google Scholar 

  35. M. Amjadi, J.L. Manzoori, J. Hassanzadeh, Anal. Lett. 42, 1539 (2009)

    Article  CAS  Google Scholar 

  36. A. Pedraza, M.D. Sicilia, S. Rubio, D. Pérez-Bendito, Anal. Bioanal. Chem. 389, 2297 (2007)

    Article  CAS  Google Scholar 

  37. M.E. Diaz Garcia, A. Sanz-Medel, Talanta 33, 255 (1986)

    Article  CAS  Google Scholar 

  38. E. Fuguet, C. Ràflos, M. Rosés, E. Bosch, Anal. Chim. Acta 548, 95 (2005)

    Article  CAS  Google Scholar 

  39. M.J. Rosen, Surfactants and Interfacial Phenomena, 3rd edition (Wiley-Interscience, USA, 2004) 123

    Google Scholar 

  40. S.M.R. Willie, K.E. Maudens, C.H. Van Peteghem, W.E.E. Lambert, J. Chromatogr. A 1098, 19 (2005)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Mohammad Amjadi, Jamshid L. Manzoori & Javad Hassanzadeh

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  1. Mohammad Amjadi
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  2. Jamshid L. Manzoori
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  3. Javad Hassanzadeh
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Correspondence to Mohammad Amjadi.

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Amjadi, M., Manzoori, J.L. & Hassanzadeh, J. Surfactant to dye binding degree method for the determination of fluvoxamine maleate and citalopram hydrobromide in pharmaceuticals. cent.eur.j.chem. 8, 536–542 (2010). https://doi.org/10.2478/s11532-010-0011-5

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  • DOI: https://doi.org/10.2478/s11532-010-0011-5

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