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Cellulose sulphuric acid as a biodegradable and reusable catalyst for the Knoevenagel condensation

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Central European Journal of Chemistry

Abstract

A green, mild and efficient method for Knoevenagel condensation of 3-formylchromone/2-chlroquinoline-3-carbaldehyde with active methylene compounds such as Meldrum’s acid/ethyl cyanoacetate using biosupported cellulose sulphuric acid (CSA) in the solid-state by grinding under solvent-free condition has been developed. This method provides several advantages including environmental friendliness, shor t reaction times, high yields and a simple work-up procedure. Moreover, the CSA was successfully reused for four cycles without significant loss of activity.

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Authors and Affiliations

  1. Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431 004, India

    Kiran F. Shelke, Suryakant B. Sapkal, Kirti S. Niralwad, Bapurao B. Shingate & Murlidhar S. Shingare

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  1. Kiran F. Shelke
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  2. Suryakant B. Sapkal
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  3. Kirti S. Niralwad
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  4. Bapurao B. Shingate
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  5. Murlidhar S. Shingare
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Correspondence to Murlidhar S. Shingare.

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Shelke, K.F., Sapkal, S.B., Niralwad, K.S. et al. Cellulose sulphuric acid as a biodegradable and reusable catalyst for the Knoevenagel condensation. cent.eur.j.chem. 8, 12–18 (2010). https://doi.org/10.2478/s11532-009-0111-2

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  • DOI: https://doi.org/10.2478/s11532-009-0111-2

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