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Spectral properties of tetraanionic porphyrin in formamide colloids of layered double hydroxides

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Central European Journal of Chemistry

Abstract

Formamide colloidal suspensions of layered double hydroxides (LDHs) with anionic dye, meso-tetrakis(4-sulfonatophenyl)porphine (TPPS) were prepared. Optical properties of these suspensions were investigated by means of absorption and fluorescence spectroscopies in the visible region. For more detailed characterization, second derivative curves of the spectra were calculated. The adsorption of the dye on LDH nanosheets led to partial molecular aggregation, reflected in significant changes of the dye optical properties. The Soret band in the absorption spectra was split into two peaks and decreased in intensity. Changes were observed also for the Q-bands. The molecular aggregation significantly quenched the emission of the dye. The low intensity emission from dye H-aggregates was identified at slightly longer wavelengths. The molecular aggregation increased with the dye/LDH ratio. At low dye loadings, the optical properties were very similar to the dye solution. The yields of the dye molecular aggregation increased with LDH surface charge.

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References

  1. T. Isobe, Y. Hotta, K. Watari, Mater. Sci. Eng. B 148, 192 (2008)

    Article  CAS  Google Scholar 

  2. U. Costantino, V. Ambrogi, M. Nocchetti, L. Perioli, Microporous Mesoporous Mater. 107, 149 (2008)

    Article  CAS  Google Scholar 

  3. S. P. Newman, W. Jones, New J. Chem. 22 105 (1998)

    Article  CAS  Google Scholar 

  4. G. Centi, S. Perathoner, Microporous Mesoporous Mater. 107, 3 (2008)

    Article  CAS  Google Scholar 

  5. E. Alvarez-Ayuso, H.W. Nugteren, Chemosphere 62, 155 (2006)

    Article  CAS  Google Scholar 

  6. D.G. Evans, D.A. Xue, Chem. Commun. 485 (2006)

  7. F. Leroux, J.P. Besse, Chem. Mater. 13, 3507 (2001)

    Article  CAS  Google Scholar 

  8. L. Tammaro, U. Costantino, A. Bolognese, G. Sammartino, G. Marenzi, A. Calignano, S. Tete, F. Mastrangelo, L. Califano, V. Vittoria, Int. J. Antimicrob. Agents 29, 417 (2007)

    Article  CAS  Google Scholar 

  9. Z.P. Liu, R.Z. Ma, M. Osada, N. Iyi, Y. Ebina, K. Takada, T. Sasaki, J. Am. Chem. Soc. 128, 4872 (2006)

    Article  CAS  Google Scholar 

  10. K. Okamoto, T. Sasaki, T. Fujita, N. Iyi, J. Mater. Chem. 16, 1608 (2006)

    Article  CAS  Google Scholar 

  11. V. Rives, M.A. Ulibarri, Coord. Chem. Rev. 181, 61 (1999)

    Article  CAS  Google Scholar 

  12. K. Lang, P. Bezdicka, J.L. Bourdelande, J. Hernando, I. Jirka, E. Kafunková, F. Kovanda, P. Kubát, J. Mosinger, D.M. Wagnerová, Chem. Mater. 19, 3822 (2007)

    Article  CAS  Google Scholar 

  13. U.A.S. Barbosa, A.M.D.C. Ferreira, V.R.L. Constantino, Eur. J. Inorg. Chem. 1577 (2005)

  14. M. Halma, F. Wypych, S.M. Drechsel, S. Nakagaki, J. Porphyrins Phthalocyanines 6, 502 (2002)

    Article  CAS  Google Scholar 

  15. J. Bujdák, Appl. Clay Sci. 34, 58 (2006)

    Article  CAS  Google Scholar 

  16. S. Takagi, M. Eguchi, D.A. Tryk, H. Inoue, J. Photochem. Photobiol., C 7, 104 (2006)

    Article  CAS  Google Scholar 

  17. N. Iyi, K. Fujii, K. Okamoto, T. Sasaki, Appl. Clay Sci. 35, 218 (2007)

    Article  CAS  Google Scholar 

  18. R. Purrello, E. Bellacchio, S. Gurrieri, R. Lauceri, A. Raudino, L.M. Scolaro, A.M. Santoro, J. Phys. Chem. B 102, 8852 (1998)

    Article  CAS  Google Scholar 

  19. T. Kobayashi, J-aggregates (Word Scientific Singapore, 1996)

  20. D.L. Akins, H.R. Zhu, Ch. Guo, J. Phys. Chem. 100, 5420 (1996)

    Article  CAS  Google Scholar 

  21. J. Bujdák, N. Iyi, Y. Kaneko, R. Sasai, Clay Miner. 38, 561 (2003)

    Article  CAS  Google Scholar 

  22. F.G. Bordwell, J.E. Bartmess, J.A. Hautala, J. Org. Chem. 43, 3095 (1978)

    Article  CAS  Google Scholar 

  23. S.M. Andrade, S.M.B. Costa, Chem. Eur. J. 12, 1046 (2006)

    Article  CAS  Google Scholar 

  24. P.G. Van Patten, A.P. Shreve, R.J. Donohoe, J. Phys. Chem. B 104, 5986 (2000)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Slovak Academy of Sciences, 845 36, Bratislava, Slovakia

    Juraj Bujdák

  2. National Institute for Materials Science (NIMS), Tsukuba, Ibaraki, 305-0044, Japan

    Nobuo Iyi

Authors
  1. Juraj Bujdák
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  2. Nobuo Iyi
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Correspondence to Juraj Bujdák.

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Bujdák, J., Iyi, N. Spectral properties of tetraanionic porphyrin in formamide colloids of layered double hydroxides. cent.eur.j.chem. 6, 569–574 (2008). https://doi.org/10.2478/s11532-008-0074-8

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  • DOI: https://doi.org/10.2478/s11532-008-0074-8

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