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Novel organic material with potential NLO application - electronic and spectroscopic properties

  • Research Article
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Central European Journal of Chemistry

Abstract

Novel dicyanoisophorone derivative, (E)-2-(3-(4-aminostyryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile, is synthesized and its structure elucidated by means of conventional and linear polarized IR-spectroscopy of oriented colloids in nematic host, 1H, 13C, 1H, 1H-COSY NMR, HPLC tandem ESI MS-MS spectrometry, UV-VIS and thermal methods. Ab initio and DFT level of theory are used to theoretically obtain the electronic structure and optical properties, both in ground and exited state, of the compound.

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Authors and Affiliations

  1. Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, 44780, Bochum, Germany

    B.B. Koleva

  2. Institut für Umweltforschung, Universität Dortmund, 44221, Dortmund, Germany

    T. Kolev & M. Spiteller

  3. Department of Organic Chemistry, Sofia University St. Kl. Ohridski, 1164, Sofia, Bulgaria

    R. Nikolova & Y. Zagraniarsky

Authors
  1. B.B. Koleva
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  2. T. Kolev
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  3. R. Nikolova
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  4. Y. Zagraniarsky
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  5. M. Spiteller
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Corresponding author

Correspondence to B.B. Koleva.

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Koleva, B., Kolev, T., Nikolova, R. et al. Novel organic material with potential NLO application - electronic and spectroscopic properties. cent.eur.j.chem. 6, 592–599 (2008). https://doi.org/10.2478/s11532-008-0061-0

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  • DOI: https://doi.org/10.2478/s11532-008-0061-0

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