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Sol-gel preparation and characterization of non-substituted and Sr-substituted lanthanum cobaltates

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Central European Journal of Chemistry

Abstract

This paper reports on the results concerning the sol-gel preparation and characterization of Sr-substituted perovskite lanthanum cobaltates La1−xSrxCoO3−δ (x = 0.0, 0.25, 0.5 and 0.75). The metal ions, generated by dissolving starting materials in diluted acetic acid were complexed by 1,2-ethanediol to obtain the precursors for the non-substituted and Sr-substituted LaCoO3. The influence of the synthesis temperature, heating time and the amount of substituent on the phase purity of La1−xSrxCoO3−δ were investigated. The phase transformations, composition and micro-structural features in the gels and polycrystalline samples were studied by thermal analysis (TG/DTA), infrared spectroscopy (IR), powder X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM).

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  1. Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

    Sigute Cizauskaite & Aivaras Kareiva

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  1. Sigute Cizauskaite
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  2. Aivaras Kareiva
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Correspondence to Aivaras Kareiva.

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Cizauskaite, S., Kareiva, A. Sol-gel preparation and characterization of non-substituted and Sr-substituted lanthanum cobaltates. cent.eur.j.chem. 6, 456–464 (2008). https://doi.org/10.2478/s11532-008-0045-0

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  • DOI: https://doi.org/10.2478/s11532-008-0045-0

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