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Excess thermodynamic quantities of D2O water calculated from its Raman O−D stretching spectra

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Central European Journal of Physics

Abstract

Excess thermodynamic functions of D2O water have been calculated from the vibrationally decoupled O−D stretching spectra of very dilute solutions of HOD in H2O. Comparison of the results with reference calorimetric data for water showed a good correspondence for excess heat capacity above the melting point of ice. The excess enthalpy at the melting point also coincides well with latent heat of melting.

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Authors and Affiliations

  1. Department of Quantum Electronics of Faculty of Physics, Sofia University, 1164, Sofia, Bulgaria

    Mircho Georgiev & Georgi Georgiev

  2. CREST, Japan Science and Technology Corporation (JST), National Institute of Advanced Industrial Science and Technology (AIST), Higashi, 305-8562, Tsukuba, Ibaraki, Japan

    Nikolay Goutev

  3. Department of Metallurgical Engineering, University of Utah, 84112, Salt Lake City, UT, U.S.A.

    Zhorro S. Nickolov

Authors
  1. Mircho Georgiev
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  2. Nikolay Goutev
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  3. Zhorro S. Nickolov
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  4. Georgi Georgiev
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Georgiev, M., Goutev, N., Nickolov, Z.S. et al. Excess thermodynamic quantities of D2O water calculated from its Raman O−D stretching spectra. centr.eur.j.phys. 3, 104–114 (2005). https://doi.org/10.2478/BF02476509

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  • DOI: https://doi.org/10.2478/BF02476509

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