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Chemical Papers

, Volume 66, Issue 4, pp 295–303 | Cite as

Formation of dioxospiroindene[1,3]thiazine and thioxoindeno[2,1-d]imidazolone derivatives from alkenylidene-hydrazinecarbothioamides

  • Alaa A. HassanEmail author
  • Ahmed M. Nour El-Din
  • Fathy F. Abdel-Latif
  • Sara M. Mostafa
  • Stefan Bräse
Original Paper

Abstract

The reaction of (substituted) alkenylidene-hydrazinecarbothioamides with 2-(1,3-dioxo-2,3-dihydro-1H-inden-2-ylidene)propanedinitrile led to the formation of 1,3-dioxospiroindene[1,3]-thiazine and thioxoindeno[2,1-d]imidazolone derivatives in modest yields. In addition, 1,3-dihydroxyindan-2-ylidenepropanedinitrile was found. Explanations of these conversions involving nucleophilic reactions and condensations are presented.

Keywords

alkenylidene-hydrazinecarbothioamides dioxospiroindene[1,3]thiazine thioxoindeno [2,1-d]imidazolone 

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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2012

Authors and Affiliations

  • Alaa A. Hassan
    • 1
    Email author
  • Ahmed M. Nour El-Din
    • 1
  • Fathy F. Abdel-Latif
    • 1
  • Sara M. Mostafa
    • 1
  • Stefan Bräse
    • 2
  1. 1.Chemistry Department, Faculty of ScienceMinia UniversityEl-MiniaEgypt
  2. 2.Institute of Organic ChemistryKarlsruhe Institute of TechnologyKarlsruheGermany

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