Central European Journal of Chemistry

, Volume 12, Issue 2, pp 220–226 | Cite as

The synthesis, structure and physical properties of lanthanide(III) complexes with nicotinic acid

  • Nuša Hojnik
  • Matjaž Kristl
  • Amalija Golobič
  • Zvonko Jagličić
  • Miha Drofenik
Research Article

Abstract

This article reports the synthesis of novel, rare-earth coordination complexes with nicotinic acid. Three compounds with the general formula Ln2[(C5H4NCOO)6(H2O)4] (Ln = Yb, 1; Ln = Gd, 2; Ln = Nd, 3) were prepared from relatively cheap and readily available reactants. Their compositions and structure were characterized by IR spectroscopy and single-crystal X-ray diffraction. The magnetic and thermogravimetric properties were also studied. The complexes consist of centrosymetric, dimeric molecules having all six nicotinato ligands coordinated with the central atom in the bidentate mode. The coordination environment of the Ln3+ for all three compounds is 8. Here we describe the crystal structure of Yb and Gd complexes with nicotinic acid.

Keywords

Lanthanides Nicotinic acid Magnetic properties X-ray structure determination Hydrogen bonds 

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Copyright information

© Versita Warsaw and Springer-Verlag Wien 2014

Authors and Affiliations

  • Nuša Hojnik
    • 1
  • Matjaž Kristl
    • 1
  • Amalija Golobič
    • 2
  • Zvonko Jagličić
    • 3
    • 4
  • Miha Drofenik
    • 1
    • 5
  1. 1.Faculty of Chemistry and Chemical EngineeringUniversity of MariborMariborSlovenia
  2. 2.Faculty of Chemistry and Chemical TechnologyUniversity of LjubljanaLjubljanaSlovenia
  3. 3.Institute of MathematicPhysics and MechanicsLjubljanaSlovenia
  4. 4.Faculty of Civil and Geodetic EngineeringLjubljanaSlovenia
  5. 5.Jožef Stefan InstituteLjubljanaSlovenia

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