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Central European Journal of Chemistry

, Volume 11, Issue 5, pp 782–789 | Cite as

Effect of hydrothermal treatment on the structure of an aluminosilicate polymer

  • Jaroslav Melar
  • Vratislav BednarikEmail author
  • Roman Slavik
  • Miroslav Pastorek
Research Article
  • 166 Downloads

Abstract

The effect of hydrothermal treatment on the structure of an aluminosilicate polymer prepared by a polycondensation reaction between silicate and hydroxoaluminate in alkaline aqueous solution was studied. The structural changes were investigated using X-ray diffraction analysis, Fourier-transform infrared spectroscopy, scanning electron microscopy imaging and thermogravimetric analysis. The results indicated that the amorphous aluminosilicate polymer transformed into a crystalline product during the hydrothermal treatment at 145°C. The crystalline phase was identified as a mineral of the zeolite group, most likely phillipsite. This transformation required an alkaline environment during the hydrothermal treatment.

Keywords

Aluminosilicate polymer Zeolite Hydrothermal treatment Polycondensation Geopolymerization 

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Copyright information

© Versita Warsaw and Springer-Verlag Wien 2013

Authors and Affiliations

  • Jaroslav Melar
    • 1
  • Vratislav Bednarik
    • 1
    Email author
  • Roman Slavik
    • 1
  • Miroslav Pastorek
    • 2
  1. 1.Department of Environment Protection Engineering, Faculty of TechnologyTomas Bata University in ZlinZlinCzech Republic
  2. 2.Department of Polymer Engineering, Faculty of TechnologyTomas Bata University in ZlinZlinCzech Republic

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