Skip to main content
SpringerLink
Log in

Analytical Method for the Residues of Triflumizole Fungicide and Its Main Metabolite in Crops by High Performance Liquid and Gas Chromatography

  • Original Paper
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

An analytical method for afungicide,(E)-4-chloro-α,α,α-trifluoro-N-(1-imidazole-l-yl-2-propoxyethylidene)-o-toluidine (triflumizole), and its metabolite 4-chloro-α,α,α-trifluoro-N-(1-amino-2-propoxyethylidene)-o-toluidine, in crops is described. These compounds in crops are extracted with methanol and then cleaned by liquid-liquid partition and column chromatography. Determinations were performed by both high performance liquid chromatography and gas chromatography. The detection limit was set at 0.02 ppm. The recoveries ranged from 72 to 101%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Nakayama, K. Ikura, K. Katsuura, S. Hashimoto and A. Nakata, J. Pesticide Sci., 5, 575 (1980).

    Article  Google Scholar 

  2. Y. Hashimoto, S. Sugimoto, Y. Soeda, A. Nakata and S. Hashimoto, J. Pesticide Sci., 15, 375 (1990).

    Article  CAS  Google Scholar 

  3. T. Gomyo, Y. Morishima, S. Yamasaki, H. Dairiki and S. Ono, Anal. Sci., 7, 579 (1991).

    Article  CAS  Google Scholar 

  4. Y. Morishima, T. Gomyo and S. Ono, Proceedings of 8th Conference on Pesticide Residue Analysis, Tokyo, 1984, p. 25.

    Google Scholar 

  5. N. Shiga, Y. Shimamura, O. Matano and S. Goto, Proceedings of 8th Conference on Pesticide Residue Analysis, Tokyo, 1984, p. 20.

    Google Scholar 

  6. N. Shiga, O. Matano and S. Goto, J. Chromatogr., 396, 327 (1987).

    Article  CAS  Google Scholar 

  7. T. Gomyo, T. Tachibana, K. Nakamura and Y. Soeda, Proceedings of 12th Conference on Pesticide Residue Analysis, Hiroshima, 1988, p. 18.

    Google Scholar 

  8. Y. Zinbo, Y. Kobayashi, O. Matano and S. Goto, Proceedings of 12th Conference on Pesticide Residue Analysis, Hiroshima, 1988, p. 14.

    Google Scholar 

  9. S. Kobayashi and T. Gomyo, Proceedings of 13th Conference on Pesticide Residue Analysis, Nikko, 1989, p. 59.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Environmental Toxicology Laboratory, Nippon Soda Co., Ltd., Takada, Odawara, 250-02, Japan

    Takeshi Gomyo, Yasushi Morishima, Teruo Tachibana, Shigeru Kobayashi & Shigeo Ono

Authors
  1. Takeshi Gomyo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yasushi Morishima
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Teruo Tachibana
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shigeru Kobayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shigeo Ono
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gomyo, T., Morishima, Y., Tachibana, T. et al. Analytical Method for the Residues of Triflumizole Fungicide and Its Main Metabolite in Crops by High Performance Liquid and Gas Chromatography. ANAL. SCI. 7, 749–756 (1991). https://doi.org/10.2116/analsci.7.749

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.7.749

Keywords

Search

Navigation