Skip to main content
Log in

Laser Induced Plasmas Observed with an Optical Imaging Spectrometer

  • Original Paper
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

Laser-induced plasmas generated by a Q-switched Nd:YAG laser were observed with an optical imaging spectrometer which was assembled from a 0.32 m spectrometer and a cooled CCD (charge-coupled device) detector. The ambient atmosphere, the kind of gas used and its pressure, influenced the emission intensities for both atomic lines and the continuum, and the volume of emissive regions of plasmas. The power density of the laser also affected the plasma characteristics. Tight focusing of laser radiation did not directly bring about a plasma of high emission intensity, because of the absorption of laser energy by the plasma itself. The importance of prevention of a gas breakdown before sample vaporization was also indicated. These effects are discussed from the viewpoints of initial cascade growth of electron number density, absorption of laser energy by the plasmas, and plasma expansion processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. Harding-Barlow, K. G. Snetsinger and K. Keil, in “Microprobe Analysis”, ed. C. A. Andersen, Chap. 12, p. 423, John Wiley & Sons, New York, 1973.

  2. A. L. Lewis, II, G. J. Beenen, J. W. Hosch and E. H. Piepmeier, Appl. Spectrosc., 37, 263 (1983).

    Article  CAS  Google Scholar 

  3. M. Kubota, J. Spectrosc. Soc. Jpn, 20, 241 (1971).

    Article  Google Scholar 

  4. L. Moenke-Blankenburg, “Laser Micro Analysis”, John Wiley & Sons, New York, 1989.

    Google Scholar 

  5. F. Leis, W. Sdorra, J. B. Ko and K. Niemax, Microchim. Acta [Wien], 1989 II, 185.

    Article  Google Scholar 

  6. L. J. Radziemski, T. R. Loree, D. A. Cremers and N. M. Hoffman, Anal. Chem., 55, 1246 (1983).

    Article  CAS  Google Scholar 

  7. M. Thompson, J. E. Goulter and F. Sieper, Analyst [London], 106, 32 (1981).

    Article  CAS  Google Scholar 

  8. T. Ishizuka and Y. Uwamino, Anal. Chem., 52, 125 (1980).

    Article  CAS  Google Scholar 

  9. Y. Iida, Spectrochim. Acta, 45B, 427 (1990).

    Article  CAS  Google Scholar 

  10. A. L. Gray, Analyst [London], 110, 551 (1985).

    Article  CAS  Google Scholar 

  11. W. J. Treytl, K. W. Marich and D. Glick, Anal. Chem., 47, 1275 (1975).

    Article  CAS  Google Scholar 

  12. Y. Iida, Appl. Spectrosc., 43, 229 (1989).

    Article  CAS  Google Scholar 

  13. C. W. Huie and E. S. Yeung, Anal. Chem., 58, 1989 (1986).

    Article  CAS  Google Scholar 

  14. C. W. Huie and E. S. Yeung, Appl. Spectrosc., 40, 863 (1986).

    Article  CAS  Google Scholar 

  15. J. W. Olesik and G. M. Hieftje, Anal. Chem., 57, 2049 (1985).

    Article  CAS  Google Scholar 

  16. H. Klocke, Spectrochim. Acta, 24B, 263 (1969).

    Article  Google Scholar 

  17. G. Dimitrov and Ts. Zheleva, Spectrochim. Acta, 39B, 1209 (1984).

    Article  CAS  Google Scholar 

  18. R. H. Scott and A. Strasheim, Spectrochim. Acta, 25B, 311 (1970).

    Article  Google Scholar 

  19. M. Thompson, S. Chenery and L. Brett, J. Anal. At. Spectrom., 5, 49 (1990).

    Article  CAS  Google Scholar 

  20. E. H. Piepmeier and D. E. Osten, Appl. Spectrosc., 25, 642 (1971).

    Article  CAS  Google Scholar 

  21. W. Bogershausen and R. Vesper, Spectrochim. Acta, 24B, 103 (1969).

    Article  Google Scholar 

  22. G. M. Weyl, in “Laser-Induced Plasmas and Applications”, ed. L. J. Radziemski and D. A. Cremers, Chap. 1, p. 1, Mercel Dekker, New York, 1989.

  23. R. G. Root, in “Laser-Induced Plasmas and Applications”, ed. L. J. Radziemski and D. A. Cremers, Chap. 2, p. 69, Mercel Dekker, New York, 1989.

  24. W. J. Treytl, K. W. Marich, J. B. Orenberg, P. W. Carr, D. C. Miller and D. Glick, Anal. Chem., 43, 1452 (1971).

    Article  CAS  Google Scholar 

  25. A. I. Barchukov, F. V. Bunkin, V. I. Konov and A. A. Lyubin, Soviet Phys. JETP, 39, 469 (1974).

    Google Scholar 

  26. Y. Iida, Spectrochim. Acta, 45B, 1353 (1980).

    Google Scholar 

  27. S. A. Ramsden and P. Savic, Nature [London], 203, 1217 (1964).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Iida, Y., Morikawa, H., Tsuge, A. et al. Laser Induced Plasmas Observed with an Optical Imaging Spectrometer. ANAL. SCI. 7, 61–64 (1991). https://doi.org/10.2116/analsci.7.61

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.7.61

Keywords

Navigation