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Synthesis and Potentiometric Selectivity Study of 14-Cyclic Dioxadiamides

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Abstract

Three compounds of a new class of ionophores, 14-cyclic dioxadiamides, were synthesized and tested for potentiometric selectivity for lithium ion in poly(vinyl chloride) membrane electrodes. Four plasticizers were studied and the addition of trioctylphosphine oxide (TOPO) was considered. One ionophore exhibited a sodium/lithium “selectivity, KpotLi, Na, by the matched potential method, of 0.012 in the presence of 1% TOPO, using o-nitrophenylphenyl ether as plasticizer. Selectivities are reported for sodium, potassium, ammonium, barium and calcium ions with respect to lithium ions.

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Authors and Affiliations

  1. Department of Chemistry, Yarmouk University, Irbid, Jordan

    Abdulrahman S. Attiyat

  2. Department of Chemistry, Faculty of Pharmacy, Zagazig University, Zagazig, Egypt

    Azza M. Kadry

  3. Department of Chemistry, Faculty of Science, Cairo University, Giza, Egypt

    Hishmatt R. Hanna & Ychia A. Ibrahim

  4. Department of Chemistry, BG-10, University of Washington, Seattle, Washington, 98195, USA

    Gary D. Christian

Authors
  1. Abdulrahman S. Attiyat
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  2. Azza M. Kadry
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  3. Hishmatt R. Hanna
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  4. Ychia A. Ibrahim
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  5. Gary D. Christian
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Attiyat, A.S., Kadry, A.M., Hanna, H.R. et al. Synthesis and Potentiometric Selectivity Study of 14-Cyclic Dioxadiamides. ANAL. SCI. 6, 233–237 (1990). https://doi.org/10.2116/analsci.6.233

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  • DOI: https://doi.org/10.2116/analsci.6.233

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