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Supersonic Jet Fluorimetry Using Spectrometric Multichannel Analyzer for Detection in Gas Chromatography

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Abstract

A supersonic jet fluorimeter with a spectrometric multichannel analyzer allows repetitive measurements of a fluorescence spectrum for gas Chromatograph effluents. A three-dimensional chromatogram is measured for a sample containing chloroanthracene derivatives by adjusting the excitation wavelength to that of a pure electronic transition for a specified molecule. By using this method, the sample molecule can readily be identified from well-resolved spectral features in the fluorescence spectrum. The detection limits are several hundred ng for 1-and 9-chloroanthracenes.

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Authors and Affiliations

  1. Department of Applied Analytical Chemistry, Faculty of Engineering, Kyushu University, Hakozaki, Fukuoka, 812, Japan

    Totaro Imasaka, Katsunori Tanaka & Nobuhiko Ishibashi

Authors
  1. Totaro Imasaka
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  2. Katsunori Tanaka
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  3. Nobuhiko Ishibashi
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Imasaka, T., Tanaka, K. & Ishibashi, N. Supersonic Jet Fluorimetry Using Spectrometric Multichannel Analyzer for Detection in Gas Chromatography. ANAL. SCI. 4, 31–35 (1988). https://doi.org/10.2116/analsci.4.31

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  • DOI: https://doi.org/10.2116/analsci.4.31

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