Abstract
The signal to background (S/B) ratio in energy dispersive X-ray fluorescence using synchrotron radiation (SR) was quantitatively analyzed. The S/B ratio, which has been significantly improved by taking advantage of the polarized nature of SR, was found to be strongly dependent on geometrical factors of the measurement system. From the analysis on the origin of the scattered background, the dependence of the S/B ratio on the geometry was quantitatively explained, mainly by the polarization properties of SR. Experimental conditions could be optimized by adjusting the degree of polarization of the incident beam and the detector solid angle.
Similar content being viewed by others
References
C. J. Sparks, Jr., in “Synchrotron Radiation Research”, Ch. 14, ed. H. Winick and S. Doniach, Plenum, New York (1980).
B. M. Gordon, Nucl. Instrum. Methods Phys. Res., 204, 223 (1982).
A. L. Hanson, K. W. Jones, B. M. Gordon, J. G. Pounds, W. M. Kwiatek, G. J. Long, M, L. Rivers and S. R. Sutton, Nucl. Instrum. Methods Phys. Res., B24/25, 400 (1987).
J. V. Gilfrich, E. F. Skelton, S. B. Qadri, J. P. Kirkland and D. J. Nagel, Anal. Chem., 55, 232 (1983).
J. M. Jaklevic, R. D. Giauque and A. C. Thompson, Nucl. Instrum. Methods Phys. Res., B10/11, 303 (1985).
D. K. Bowen, T. S. Davies and T. Ambridge, J. Appl. Phys., 58, 260 (1985).
W. Petersen, P. Ketelsen, A. Knochel and R. Pausch, Nucl. Instrum. Methods Phys. Res., A246, 731 (1986).
A. Iida, K. Sakurai, A. Yoshinaga and Y. Gohshi, Nucl. Instrum. Methods Phys. Res., A246, 736 (1986).
A. Iida, K. Sakurai, T. Matsushita and Y. Gohshi, Nucl. Instrum. Methods Phys. Res., 228, 556 (1985).
A. L. Hanson, Nucl. Instrum. Methods Phys. Res., A243, 583 (1986).
T. G. Dzubay, B. V. Jarret and J. M. Jaklevic, Nucl. Instrum. Methods Phys. Res., 115, 297 (1974).
H. Winick, in “Synchrotron Radiation Research”, Ch. 2, ed. H. Winick and S. Doniach, Plenum, New York (1980).
F. S. Goulding and J. M. Jaklevic, Nucl. Instrum. Methods Phys. Res., 142, 323 (1977).
G. Materlik and P. Suortti, J. Appl. Cryst., 17, 7 (1984).
T. Ishikawa, S. Annaka and K. Kohra, in “Photon Factory Activity Report 1982/83”, VI - 112, (1983).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sakurai, K., Iida, A. & Gohshi, Y. Analysis of Signal to Background Ratio in Synchrotron Radiation X-Ray Fluorescence. ANAL. SCI. 4, 3–7 (1988). https://doi.org/10.2116/analsci.4.3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.4.3