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Solvent Extraction of Copper(II) in Aqueous Thiocyanate Solutions with 4-Methyl-2-pentanone

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Abstract

Solvent extractions of copper(II) from aqueous thiocyanate solutions into carbon tetrachloride containing benzoyltrifluoroacetone and into 4-methyl-2-pentanone were studied. From the data of the former extraction system, the stability constants of metal thiocyanate complexes in the aqueous phase were determined. From the data of the latter system, the extraction constants for the CuSCN+ClO4-, Cu(SCN)2 and Na+Cu(SCN)3- species were obtained. The extraction curve of this metal ion as well as those of nickel(II), cobalt(II), zinc(II), cadmium(II), mercury(II) and lead(II) in this liquid-liquid system were considered from the standpoint of the stability and extractability of the complexes.

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References

  1. T. Sekine, R. Murai and M. Iguchi, Nippon Kagaku Zasshi, 92, 412 (1971).

    Article  CAS  Google Scholar 

  2. R. Murai, S. Iwahori and T. Sekine, Bull. Chem. Soc. Jpn., 50, 1315 (1977).

    Article  CAS  Google Scholar 

  3. H. Moriya and T. Sekine, Bull. Chem. Soc. Jpn.], 44, 3347 (1971)

    Article  Google Scholar 

  4. R. Murai, S. Iwahori and T. Sekine, Bunseki Kagaku, 31, 413 (1982).

    Article  CAS  Google Scholar 

  5. T. Sekine and T. Ishii, Bull. Chem. Soc. Jpn., 43, 2422 (1970).

    Article  CAS  Google Scholar 

  6. S. Kusakabe and T. Sekine, Bull. Chem. Soc. Jpn., 54, 2533 (1981).

    Article  CAS  Google Scholar 

  7. Elena Spaccamela-Marchetti and Maria Teresa Cereti Mazza, Chim. e ind. (Mirano) 43, 133 (1961); Chem. Abstr., 55, 16100 (1961).

    Google Scholar 

  8. A. K. De and A. K. Sen, Separ. Sci., 1, 641 (1966).

    CAS  Google Scholar 

  9. R. Murai, S. Iwahori and T. Sekine, J. Inorg. Chem., 39, 363 (1977).

    Google Scholar 

  10. T. Sekine and D. Dyrssen, Anal. Chim. Acta., 45, 433 (1969).

    Article  CAS  Google Scholar 

  11. Y. Hasegawa, T. Ishii and T. Sekine, Bull Chem. Soc. Jpn., 44, 275 (1971).

    Article  CAS  Google Scholar 

  12. Y. Hasegawa and T. Sekine, J. Inorg. Nucl. Chem., 36, 421 (1974).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Science University of Tokyo, Kagurazaka, Shinjuku, Tokyo, 162, Japan

    Tatsumu Morimoto, Shigeyuki Ochiai & Tatsuya Serine

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  1. Tatsumu Morimoto
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  2. Shigeyuki Ochiai
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  3. Tatsuya Serine
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Morimoto, T., Ochiai, S. & Serine, T. Solvent Extraction of Copper(II) in Aqueous Thiocyanate Solutions with 4-Methyl-2-pentanone. ANAL. SCI. 4, 255–259 (1988). https://doi.org/10.2116/analsci.4.255

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  • DOI: https://doi.org/10.2116/analsci.4.255

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