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Adsorption Effects on Retention Behavior of Hydrocarbon Solutes in Gas Chromatography by Use of Nonpolar Stationary Liquid Phase Squalane

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Abstract

The solute retention mechanism in gas-liquid chromatography was studied for the hydrocarbon solute-nonpolar stationary liquid phase (squalane) system. The retention volume of the solute and the specific surface area of the liquid-coated, modified alumina were determined as a function of the liquid loading. On the basis of the previous reasoning, distribution constants for the bulk solution partition and some adsorption equilibria taking part in the solute retention could be estimated. The results prove to be quite different from those of the polar liquid phases used previously: that is, squalane formed a bulk liquid layer on the modified alumina after the solid support was completely covered with the monolayer.

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References

  1. J. R. Conder, D. C. Locke and J. H. Purnell, J. Phys. Chem., 73, 700 (1969).

    Article  CAS  Google Scholar 

  2. V. G. Berezkin, J. Chromatogr., 65, 227 (1972).

    Article  CAS  Google Scholar 

  3. V. G. Berezkin, J. Chromatogr., 159, 358 (1978).

    Article  Google Scholar 

  4. Z. Suprynowicz, A. Wakdsmundzki and W. Rudzinski, J. Chromatogr., 67, 21 (1972).

    Article  CAS  Google Scholar 

  5. A. Wakdsmundzki, W. Rudzinski and Z. Suprynowicz, J. Chromatogr., 74, 3 (1972).

    Article  Google Scholar 

  6. J. A. Jönsson and L. Mathiasson, J. Chromatogr., 179, 1 (1979).

    Article  Google Scholar 

  7. D. F. Fritz, A. Sahil and E. Sz. Kovats, J. Chromatogr., 186, 63 (1979).

    Article  CAS  Google Scholar 

  8. K. Naito, H. Ogawa, S. Moriguchi and S. Takei, J. Chromatogr., 299, 73 (1984).

    Article  CAS  Google Scholar 

  9. K. Naito and S. Takei, J. Chromatogr., 190, 21 (1980).

    Article  CAS  Google Scholar 

  10. K. Naito, N. Ohwada, S. Moriguchi and S. Takei, J. Chromatogr., 330, 193 (1985).

    Article  CAS  Google Scholar 

  11. K. Naito, S. Wada and S. Takei, Anal. Sci., 4, 105 (1988).

    Article  CAS  Google Scholar 

  12. S. J. Gregg and K. S. W. Sing, “Adsorption, Surface Area and Porosity”, p. 67, Academic Press, London (1967).

    Google Scholar 

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Authors and Affiliations

  1. Department of Industrial Chemistry, Faculty of Engineering, Ibaraki University, Hitachi, 316m, Japan

    Kunishige Naito, Hiroyuki Ogawa, Shinkichi Igarashi & Shinsuke Takei

Authors
  1. Kunishige Naito
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  2. Hiroyuki Ogawa
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  3. Shinkichi Igarashi
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  4. Shinsuke Takei
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Naito, K., Ogawa, H., Igarashi, S. et al. Adsorption Effects on Retention Behavior of Hydrocarbon Solutes in Gas Chromatography by Use of Nonpolar Stationary Liquid Phase Squalane. ANAL. SCI. 4, 185–190 (1988). https://doi.org/10.2116/analsci.4.185

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  • DOI: https://doi.org/10.2116/analsci.4.185

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