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Detection of Chlorine in a Non-aqueous Solution via Anodic Oxidation and a Photochemical Reaction

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Abstract

In this study, we developed a new chlorine gas detection method using anodic oxidation and a photochemical reaction. Chlorine gas was temporarily solvated with an aprotic polar solvent having an extensive potential range in the positive direction, and the solvated chlorine molecule was detected by an anodic oxidation reaction. In addition, when combined with ultraviolet light irradiation, we could detect high sensitivity using the photochemical reaction.

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Acknowledgments

This work was supported by JSPS KAKENHI Grant Number 17K18315.

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Authors and Affiliations

  1. Department of Materials Chemistry, National Institute of Technology, Asahikawa College, 2-2-1-6 Shunkodai, Asahikawa, Hokkaido, 071-8142, Japan

    Shogo Nakagawa, Hajime Nishimura & Fumihiro Koder

  2. Graduate School of Environmental Science, Hokkaido University, N10W5, Kite, Sapporo, 060-0810, Japan

    Shogo Nakagawa

  3. Graduate School of Chemical Sciences and Engineering, Hokkaido University, N13W8, Kita, Sapporo, 060-0810, Japan

    Hajime Nishimura

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  1. Shogo Nakagawa
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  2. Hajime Nishimura
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  3. Fumihiro Koder
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Nakagawa, S., Nishimura, H. & Koder, F. Detection of Chlorine in a Non-aqueous Solution via Anodic Oxidation and a Photochemical Reaction. ANAL. SCI. 34, 1–4 (2018). https://doi.org/10.2116/analsci.34.1

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  • DOI: https://doi.org/10.2116/analsci.34.1

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