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A Novel Copper(II) Sensor Based on a Unique Water-soluble Porphyrin

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Abstract

A unique water-soluble porphyrin [5,10,15,20-tetra(3-ethoxy-4-hydroxy-5-sulfonate)phenyl porphyrin, H2TEHPPS] was designed and synthesized, which could be used as a potential sensor for the determination of Cu2+. Studies were performed in the solution. The concentration of H2TEHPPS was 5 μmol L–1. The optical properties of H2TEHPPS were investigated based on the absorption spectra. The results show that the absorbance of H2TEHPPS at 417 nm is directly proportional to the concentration of Cu2+ in the range of 0–2.5 μmol L–1. H2TEHPPS can thus be used as a novel class of Cu2+ sensors.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21207047), the State Major Project for Science and Technology Development, China (No. 2013YQ47078102-3), the Science-Technology Development Project of Jilin Province of China (No. 20130206014GX, 20140623007TC, 20150204017YY), the Natural Science Foundation of Jilin Province of China (20160101314JC) and the Program for the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Open Project, Jilin University, China (No. 2014-07).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130023, People’s Republic of China

    Qiang Fei, Hongyan Shan, Yanfu Huan, Zhiquan Zhang, Hongyu Mi, Hui Xu & Guodong Feng

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Guanghua Li

  3. Changchun Institute of Metrology, Changchun, 130012, P. R. China

    Fei Chen

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  1. Qiang Fei
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  2. Hongyan Shan
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  3. Yanfu Huan
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  4. Zhiquan Zhang
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  5. Hongyu Mi
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  6. Hui Xu
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  7. Guanghua Li
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  8. Fei Chen
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  9. Guodong Feng
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Correspondence to Guodong Feng.

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Fei, Q., Shan, H., Huan, Y. et al. A Novel Copper(II) Sensor Based on a Unique Water-soluble Porphyrin. ANAL. SCI. 32, 745–749 (2016). https://doi.org/10.2116/analsci.32.745

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  • DOI: https://doi.org/10.2116/analsci.32.745

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