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Simultaneous Determination of Pyridine-Triphenylborane Anti-Fouling Agent and Its Degradation Products in Paint-Waste Samples Using Capillary Zone Electrophoresis with Field-Amplified Sample Injection

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Abstract

We proposed a capillary zone electrophoresis (CZE) procedure using field-amplified sample injection (FASI) for the simultaneous determination of pyridine-triphenylborane (PTPB) and its degradation products: diphenylborinic acid (DPB), phenylboronic acid (MPB), and phenol. The LODs for PTPB, DPB, MPB, and phenol were, respectively, 0.85, 0.88, 44, and 28 μg L− 1. The RSDs (n = 4) for the analytes listed above were in respective ranges of 6.2 – 14, 5.9 – 10, and 0.49 – 0.62% for the peak area, peak height, and migration time. The compounds were extracted from paint-waste samples collected from shipyards using a siliga-gel column. The extract was dissolved with acetonitrile containing 1% (v/v) pyridine. The samples were then analyzed using CZE, revealing respective concentrations of 0.076 – 0.53, 0.015 – 0.36, 1.7 – 22, and 1.2 – 13 μg g−1. The proposed FASI-CZE method is a simple and promising procedure that is expected to be useful for the determination of PTPB and its degradation products in paint wastes.

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Authors and Affiliations

  1. Graduate School of Maritime Sciences, Kobe University, 5-1-1 Fukaeminami-machi, 658-0022, Higashinada, Kobe, Japan

    Netnapit Kaewchuay, Keiichi Fukushi, Ai Tsuboi & Hideo Okamura

  2. Graduate School of Human Development and Environment, Kobe University, 3-11 Tsurukabuto, 657-8501, Nada, Kobe, Japan

    Keiitsu Saito

  3. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, 739-8527, Higashi-hiroshima, Hiroshima, Japan

    Takeshi Hirokawa

Authors
  1. Netnapit Kaewchuay
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  2. Keiichi Fukushi
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  3. Ai Tsuboi
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  4. Hideo Okamura
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  5. Keiitsu Saito
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  6. Takeshi Hirokawa
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Correspondence to Keiichi Fukushi.

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Kaewchuay, N., Fukushi, K., Tsuboi, A. et al. Simultaneous Determination of Pyridine-Triphenylborane Anti-Fouling Agent and Its Degradation Products in Paint-Waste Samples Using Capillary Zone Electrophoresis with Field-Amplified Sample Injection. ANAL. SCI. 28, 1191–1196 (2012). https://doi.org/10.2116/analsci.28.1191

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  • DOI: https://doi.org/10.2116/analsci.28.1191

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