Abstract
We report on a chemical-sensing method based on the silica-micelle mesophase wherein both a fluoroionophore and a masking agent are embedded. Using this method, a highly selective detection of metal ions in an aqueous solution has been successfully demonstrated. Furthermore, simultaneous analyses of multisamples using a sensor array composed of functionalized mesoporous thin films were demonstrated for the first time.
References
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, and E. W. Sheppard, J. Am. Chem. Soc., 1992, 114, 10834.
C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, and J. S. Beck, Nature, 1992, 359, 710.
M. Ogawa, J. Photochem. Photobiol., C, 2002, 3, 129.
H. Yang, A. Kuperman, N. Coombs, S. Mamiche-Afara, and G. A. Ozin, Nature, 1996, 379, 703.
M. Ogawa, Chem. Commun., 1996, 1149.
C. J. Brinker, Y. Lu, A. Sellinger, and H. Fan, Adv. Mater., 1999, 11, 579.
H. Fan, Y. Lu, A. Stump, S. T. Reed, T. Baer, R. Schunk, V. Perez-Luna, G. P. Lopez, C. J. Brinker, Nature, 2000, 405, 56.
Y. Lu, R. Ganguli, C. A. Drewien, M. T. Anderson, C. J. Brinker, W. Gong, Y. Guo, H. Soyez, B. Dunn, M. H. Huang, and J. I. Zink, Nature, 1997, 389, 364.
J. D. Badjic and N. M. Kostic, J. Phys. Chem. B, 2001, 105, 7482.
A. Yamaguchi, F. Uejo, T. Yoda, T. Uchida, Y. Tanamura, T. Yamashita, and N. Teramae, Nat. Mater., 2004, 3, 337.
A. Fernandez-Gutierrez and A. Munoz de la Pena, “Molecular Luminescence Spectroscopy. Methods and Applications: Part 1”, ed. S. G. Schulman, 1985, Wiley, New York, 371 – 546.
P. N. Minoofar, R. Hernandez, S. Chia, B. Dunn, J. I. Zink, and A.-C. Franville, J. Am. Chem. Soc., 2002, 124, 14388.
F. Salinas, A. Munoz de la Pena, and M. S. Duran, Anal. Lett., 1988, 21, 1457.
E. J. Cho and F. V. Bright, Anal. Chem., 2002, 74, 1462.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Rights and permissions
About this article
Cite this article
Suto, Y., Uchida, T., Kumata, H. et al. Chemical Sensing of Metal Ions Using a Silica-Micelle Mesophase Doubly Functionalized by a Fluorogenic Ionophore and a Masking Agent. ANAL. SCI. 27, 673–674 (2011). https://doi.org/10.2116/analsci.27.673
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.27.673