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Chemiluminescence Detection of Five-membered Heteroaromatic Compounds Using Electrogenerated Tris(2,2′-bipyridine)-ruthenium(III)

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Abstract

Heteroaromatic compounds, such as 2,5-dimethylthiophene, 2,5-dimethylpyrrole, and 2,5-dimethylfuran, were found to act as reducing agents for the tris(2,2′-bipyridme)ruthenium(III), Ru(bpy)33+, chemiluminescent reaction. In order to characterize the chemiluminescent reaction of Ru(bpy)33+ with heteroaromatic compounds, we have investigated various mono-, di-, and tri-heteroaromatic compounds. The n-electron density and stability of aromatic rings influence the chemiluminescent efficiency of the reaction. Above all, 2,5-dimethylthiophene produced strong chemiluminescence under acidic conditions. In addition, we confirmed that the rate of the chemiluminescent reaction of Ru(bpy)33+ with 2,5-dimethylthiophene is very fast.

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Authors and Affiliations

  1. Department of Environmental Chemistry, Kanazawa Institute of Technology, 7-1 Ohgigaoka, Nonoichi, Ishikawa, 921-8501, Japan

    Hitoshi Kodamatani & Yu Komatsu

  2. Department of Applied Science, Okayama University of Science, 1-1 Ridaicho, Okayama, 700-0005, Japan

    Shigeo Yamazaki

  3. Division of Natural Environment and Chemistry, Faculty of Human Development, Kobe University, 3-11 Tsurukabuto, Nada, Kobe, 657-8501, Japan

    Keiitsu Saito

Authors
  1. Hitoshi Kodamatani
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  2. Yu Komatsu
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  3. Shigeo Yamazaki
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  4. Keiitsu Saito
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Corresponding author

Correspondence to Keiitsu Saito.

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Kodamatani, H., Komatsu, Y., Yamazaki, S. et al. Chemiluminescence Detection of Five-membered Heteroaromatic Compounds Using Electrogenerated Tris(2,2′-bipyridine)-ruthenium(III). ANAL. SCI. 23, 407–411 (2007). https://doi.org/10.2116/analsci.23.407

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  • DOI: https://doi.org/10.2116/analsci.23.407

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