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Preparation and evaluation of molding-type solid-phase extraction media binding with commercially available adhesives

Abstract

A fabrication method of molding-type solid-phase extraction media (M-SPEM) bound with commercially available adhesive is presented. Six pieces of M-SPEM were prepared by heating each kneaded product of a particulate sorbent and an adhesive inserted into a six-hole cylindrical mold for hardening under an open system and normal pressure. The particulate sorbent contained in M-SPEM was divinylbenzene-based reversed-phase mode solid-phase extractants that we have reported. An examination of several adhesives showed that the moldability of M-SPEM depended on the composition and properties of the adhesive. The optimized procedure can be used to prepare an M-SPEM containing an 85 wt% particulate sorbent (particulate sorbent/adhesive, 100 mg/17 mg; particle diameter, 90–150 µm), and the M-SPEM has a specific surface area of about 500 m2/g. The established procedure in this study can bind particulate sorbents together, which showed almost no reductions in the adsorption property and liquid permeability compared with those of the particulate sorbent.

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Acknowledgements

This study was partly supported by JSPS KAKENHI Grant no. 20K05571 (Grant-in-Aid for Scientific Research (C) for H.M.) and 19H02751 (Grant-in-Aid for Scientific Research (B) for N.T.). The authors would like to thank Enago (www.enago.jp) for the English language review.

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Correspondence to Hiroya Murakami.

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Advance Publication Released Online by J-STAGE October 22, 2021.

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Miki, Y., Murakami, H., Iida, K. et al. Preparation and evaluation of molding-type solid-phase extraction media binding with commercially available adhesives. ANAL. SCI. 38, 307–315 (2022). https://doi.org/10.2116/analsci.21P265

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  • DOI: https://doi.org/10.2116/analsci.21P265

Keywords

  • Molding
  • Commercially available adhesive
  • Solid-phase extraction
  • Particulate sorbent
  • Reversed phase