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Electronic Structure Analysis of Iron(III)-Porphyrin Complexes by X-ray Absorption Spectra at the C, N and Fe K-Edges

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Abstract

X-ray absorption near edge structure (XANES) measurements at the C, N, and Fe K absorption edges were performed for iron(III)-tetraphenylporphyrin (FeTPP), iron(III)-tetrakis(p-carboxyphenyl)porphyrin (FeTCPP), and iron(III)-tetrakis(p-sulfonatophenyl)porphyrin (FeTSPP). The spectral shapes differ in the Fe K XANES, but not in C and N K XANES among FeTPP, FeTCPP, and FeTSPP. Crosschecks of XANES data for C, N, and Fe K absorption edges in combination with discrete variational (DV)-Xα molecular orbital (MO) calculations indicate that each p-electron-withdrawing group on four meso-phenyl substitutes in an Fe(III)-porphyrin complex brings about a unique electron state through the complex because of the electron-withdrawal strength, itself. Consequently, they affect the positive charge of the center Fe(III) ion.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, 814-0180, Japan

    Hisao Yamashige, Tsutomu Kurisaki & Hisanobu Wakita

  2. Advanced Materials Institute, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, 814-0180, Japan

    Shuji Matsuo & Hisanobu Wakita

  3. Center for X-Ray Optics, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA

    Rupert C. C. Perera

Authors
  1. Hisao Yamashige
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  2. Shuji Matsuo
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  3. Tsutomu Kurisaki
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  4. Rupert C. C. Perera
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  5. Hisanobu Wakita
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Correspondence to Hisanobu Wakita.

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Yamashige, H., Matsuo, S., Kurisaki, T. et al. Electronic Structure Analysis of Iron(III)-Porphyrin Complexes by X-ray Absorption Spectra at the C, N and Fe K-Edges. ANAL. SCI. 21, 309–314 (2005). https://doi.org/10.2116/analsci.21.309

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  • DOI: https://doi.org/10.2116/analsci.21.309

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