Skip to main content
SpringerLink
Log in

Uptake of Cycloalkanes and Bicyclic Aromatic Compounds by Ion-Exchange Resins from Aqueous Solutions

  • Notes
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The uptakes of cycloalkanes (C5 - C8) and bicyclic aromatic compounds (naphthalene, biphenyl, and azulene) by both strong acid cation (Dowex 50W-X4 and X8) and strong base anion (Dowex 1-X4 and X8) exchange resins have been studied in aqueous solutions at 25°C; their distribution constants (K) have been determined. The relationship between the octanol-water partition coefficient and the resin affinity for solutes has been analyzed. The K values of three aromatic compounds were found to be much higher than expected from the octanol-water partition coefficients. This is probably due to the n interaction of aromatic rings with the resin matrix. Microscopic observations revealed that azulene molecules are uniformly distributed inside a resin particle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. W. Davies and G. G. Thomas, J. Chem. Soc, 1951. 2624.

    Google Scholar 

  2. D. Reichenberg and W. F. Wall, J. Chem. Soc, 1956, 3364.

    Google Scholar 

  3. I. Sanemasa, M. Nakahara, and J.-Z. Zheng, Anal. Sci., 2003, 19, 949.

    Article  CAS  Google Scholar 

  4. R. L. Gustafson and J. A. Lirio, Ind. Eng. Chem. Prod. Res. Develop., 1968, 7, 116.

    CAS  Google Scholar 

  5. G. E. Janauer and I. M. Turner, J. Phys. Chem., 1969, 73, 2194.

    Article  CAS  Google Scholar 

  6. L. M. Jahangir, L. Olsson, and O. Samuelson, Talanta, 1975, 22, 973.

    Article  CAS  Google Scholar 

  7. I. Sanemasa, K. Ishibashi, M. Kumamaru, and T. Deguchi, Bull. Chem. Soc. Jpn., 1989, 62, 2908.

    Article  Google Scholar 

  8. H.-B. Kim, M. Hayashi, K. Nakatani, N. Kitamura, K. Sasaki, J. Hotta, and H. Masuhara, Anal. Chem., 1996, 68, 409.

    Article  CAS  Google Scholar 

  9. B. Tamamushi and K. Tamaki, Trans. Faraday Soc, 1959, 55, 1013.

    Article  CAS  Google Scholar 

  10. M. H. Abraham, H. S. Chadha, G. W. Whiting, and R. C. Mitchell, J. Pharm. Sci., 1994, 83, 1085.

    Article  CAS  Google Scholar 

  11. T. Kawakita, T. Ogura, M. Saeki, and H. Hayasaki, Agric. Biol. Chem., 1990, 54, 1.

    CAS  Google Scholar 

  12. P. Li and A. K. Sengupta, Environ. Sci. Technol., 1998, 32, 3756.

    Article  CAS  Google Scholar 

  13. J. Gregory and M. J. Semmens, J. Chem. Soc, Faraday Trans. 1,1972, 68, 1045.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Science, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan

    Isao Sanemasa, Megumi Izuno & Yuka Fujii

Authors
  1. Isao Sanemasa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Megumi Izuno
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yuka Fujii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Isao Sanemasa.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sanemasa, I., Izuno, M. & Fujii, Y. Uptake of Cycloalkanes and Bicyclic Aromatic Compounds by Ion-Exchange Resins from Aqueous Solutions. ANAL. SCI. 21, 1541–1544 (2005). https://doi.org/10.2116/analsci.21.1541

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.21.1541

Search

Navigation