Skip to main content
SpringerLink
Log in

Separation of Inorganic Anions Using an 18-Crown-6-ether-modified Organic Polymer Monolithic Stationary Phase in Capillary Ion Chromatography

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

In this study, a monolithic organic polymer stationary phase was modified using 18-crown-6-ether for use in capillary ion chromatography. Its use in the separation of inorganic anions was investigated. The monolithic stationary phase was obtained by chemically bonding 2-aminomethyl-18-crown-6-ether to a polymer skeleton comprising glycidyl methacrylate and ethylene glycol dimethacrylate. The optimum level of the loading of 2-aminomethyl-18-crown-6-ether onto the stationary phase was investigated. The resulting stationary phase was used to investigate the influence of the eluent cation, the concentration of the eluent, and the pH of the eluent on the separation of inorganic anions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Takayama, L. W. Lim, and T. Takeuchi, Anal. Sci., 2017, 33, 631.

    Article  CAS  Google Scholar 

  2. T. Umemura, Chromatography, 2019, 40, 143.

    Article  CAS  Google Scholar 

  3. S. Yoshii, M. Mori, D. Kozaki, T. Hosokawa, and H. Itabashi, Anal. Sci., 2019, 35, 1117.

    Article  CAS  Google Scholar 

  4. C. Ishii, A. Furusho, C.-L. Hsieh, and K. Hamase, Chromatography, 2020, 47, 1.

    Article  Google Scholar 

  5. H. Minakuchi, K. Nakanishi, N. Soga, N. Ishizuka, and N. Tanaka, Anal. Chem., 1996, 68, 3498.

    Article  CAS  Google Scholar 

  6. H. Minakuchi, K. Nakanishi, N. Soga, N. Ishizuka, and N. Tanaka, J. Chromatogr. A, 1997, 762, 135.

    Article  CAS  Google Scholar 

  7. N. Ishizuka, H. Minakuchi, K. Nakanishi, N. Soga, and N. Tanaka, J. Chromatogr. A, 1998, 797, 133.

    Article  CAS  Google Scholar 

  8. N. Tanaka, H. Nagayama, H. Kobayashi, T. Ikegami, K. Hosoya, N. Ishizuka, H. Minakuchi, K. Nakanishi, K. Cabrera, and D. Lubda, J. High Resolut. Chromatogr., 2000, 23, 111.

    Article  CAS  Google Scholar 

  9. N. Ishizuka, H. Minakuchi, K. Nakanishi, N. Soga, H. Nagayama, K. Hosoya, and N. Tanaka, Anal. Chem., 2000, 72, 1275.

    Article  CAS  Google Scholar 

  10. N. Tanaka, H. Kobayashi, K. Nakanishi, H. Kobayashi, and N. Ishizuka, Anal. Chem., 2001, 73, 420A.

    Article  CAS  Google Scholar 

  11. N. Ishizuka, H. Kobayashi, H. Minakuchi, K. Nakanishi, K. Hirao, K. Hosoya, T. Ikegami, and N. Tanaka, J. Chromatogr. A, 2002, 960, 85.

    Article  CAS  Google Scholar 

  12. N. Tanaka, H. Kobayashi, N. Ishizuka, H. Minakuchi, K. Nakanishi, K. Hosoya, and T. Ikegami, J. Chromatogr. A, 2002, 965, 35.

    Article  CAS  Google Scholar 

  13. L. W. Lim, K. Hirose, S. Tatsumi, H. Uzu, M. Mizukami, and T. Takeuchi, J. Chromatogr. A, 2004, 1033, 205.

    Article  CAS  Google Scholar 

  14. S. Xie, R. W. Allington, J. M. J. Frechet, and F. Svec, Adv. Biochem. Eng., 2002, 76, 87.

    CAS  Google Scholar 

  15. M. R. Buchmeiser, Polymer, 2007, 48, 2187.

    Article  CAS  Google Scholar 

  16. F. Svec and J. M. J. Frechet, Anal. Chem., 1992, 64, 820.

    Article  CAS  Google Scholar 

  17. S. Xie, F. Svec, and J. M. J. Frechet, J. Chromatogr. A, 1997, 775, 65.

    Article  CAS  Google Scholar 

  18. E. C. Peters, M. Petro, F. Svec, and J. M. J. Frechet, Anal. Chem., 1997, 69, 3646.

    Article  CAS  Google Scholar 

  19. F. Furqani, L. W. Lim, and T. Takeuchi, J. Idn. Chem. Soc., 2019, 2, 81.

    Article  Google Scholar 

  20. X. Mao, X. Cheng, Z. Lv, F. Xiao, L. Liu, X. Cheng, and W. Ni, Anal. Sci., 2021, 37, 261.

    Article  CAS  Google Scholar 

  21. P. R. Haddad and P. E. Jackson, “Ion Chromatography: Principles and Applications (J. Chromatogr. Library Vol. 46)”, 1990, Elsevier, Amsterdam, London, New York, Tokyo, 233.

    Google Scholar 

  22. J. D. Lamb and R. G. Smith, J. Chromatogr. A, 1991, 546, 73.

    Article  CAS  Google Scholar 

  23. M. W. Laubi and B. Campus, J. Chromatogr. A, 1995, 706, 103.

    Article  Google Scholar 

  24. K. Ohta, K. Kusumoto, Y. Takao, A. Towata, S. Kawakami, M. Ohashi, and T. Takeuchi, Chromatographia, 2003, 58, 171.

    CAS  Google Scholar 

  25. T. Takeuchi and L. W. Lim, Anal. Sci., 2011, 27, 1019.

    Article  CAS  Google Scholar 

  26. I. Kawase, L. W. Lim, and T. Takeuchi, Chromatographia, 2017, 80, 1089.

    Article  CAS  Google Scholar 

  27. “Globally Harmonized System of Classification and Labelling of Chemicals (GHS)”, 2015, 6th ed., United Nations Economic Commission for Europe (UNECE).

  28. K. H. Hyun, J. S. Jin, and W. Lee, J. Chromatogr. A, 1998, 822, 155.

    Article  Google Scholar 

  29. H. Nagata, Bulletin ofOsaka University ofPharmaceutical Sciences (in Japanese), 2010, 4, 105.

    Google Scholar 

  30. T. Takeuchi, K. Tokunaga, and L. W. Lim, Anal. Sci., 2013, 29, 423.

    Article  CAS  Google Scholar 

  31. L. W. Lim, K. Tokunaga, and T. Takeuchi, Chromatography, 2014, 35, 95.

    Article  Google Scholar 

  32. A. Rahayu, L. W. Lim, and T. Takeuchi, Talanta, 2015, 134, 232.

    Article  CAS  Google Scholar 

  33. JIS K 0102, “Testing Methods for Industrial Wastewater”, 2016, Japanese Industrial Standards Committee, Tokyo.

Download references

Acknowledgements

This study was partly supported by JSPS Grants-in-Aid for Scientific Research (KAKENHI, grant number: 18K05168), Japan.

Author information

Authors and Affiliations

  1. Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Kenichi Tsuge, Lee Wah Lim & Toyohide Takeuchi

Authors
  1. Kenichi Tsuge
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lee Wah Lim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Toyohide Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Lee Wah Lim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tsuge, K., Lim, L.W. & Takeuchi, T. Separation of Inorganic Anions Using an 18-Crown-6-ether-modified Organic Polymer Monolithic Stationary Phase in Capillary Ion Chromatography. ANAL. SCI. 37, 845–850 (2021). https://doi.org/10.2116/analsci.20P279

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.20P279

Keywords

Search

Navigation