Skip to main content
SpringerLink
Log in

Novel Potentiometric Screen-printed Carbon Electrodes for Bisphenol S Detection in Commercial Plastic Samples

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

Novel miniaturized poly(vinyl chloride) matrix membrane sensors based on screen-printed carbon electrodes and responsive to bisphenol S (BPS) were formulated. Polymeric membranes are based on an ion-pair complex of BPS anion with an Aliquat 336S counter cation. A solid conductive contact of multi- walled carbon nanotubes (MWCNTs) was used on screen-printed carbon platforms. After drop-casting and drying of the MWCNTs on a carbonaceous substrate, it was coated with a layer of polymeric poly(vinyl chloride) PVC sensing membrane containing the recognition complex. Prepared electrodes revealed a near- Nernstian response towards BPS with a–28.2 ± 0.8 mV/decade anionic slope, 0.02 μg/mL detection limit and 2.5 × 10–7–1.0 × 10–3 M concentration range (r2 =–0.9994). Signals were recorded in a 30 mM HCO3–/CO32– buffer, pH 10, with fast response times <10 s. A suggested sensing system was effectively applied in the quantitative determination of diminished BPS levels released from plastic bottle samples, and obtained results were statistically assessed against a chromatographic HPLC independent reference method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S.P. Rwei, S.C. Kao, G.S. Liou, K.C. Cheng, W. Guo, Colloid Polym. Sci., 2003, 281, 407.

    Article  CAS  Google Scholar 

  2. M.R. Kim, H.S. Kim, D.W. Park, J.K. Lee, React. Kinet. Catal. Lett., 2001, 72, 373.

    Article  CAS  Google Scholar 

  3. J. Gong, J. Ran, D.Y. Chen, Y. Yu, X.X. Ma, Environ. Monit. Assess., 2009, 756, 199.

    Article  Google Scholar 

  4. G. Cao, J. Lu, G. Wang, J. Environ. Sci., 2012, 24, 846.

    Article  CAS  Google Scholar 

  5. K. Pivnenko, G.A. Pedersen, E. Eriksson, T.F. Astrup, Waste Manage., 2015, 44, 39.

    Article  CAS  Google Scholar 

  6. G. Russo, F. Barbato, E. Cardone, M. Fattore, S. Albrizio, L. Grumetto, J. Environ. Sci. Health, Part B, 2018, 53, 116.

    Article  CAS  Google Scholar 

  7. M. Ike, M.Y. Chen, E. Danzl, K. Sei, M. Fujita, Water Sci. Technol., 2006, 53, 153.

    Article  CAS  PubMed  Google Scholar 

  8. A. Belfroid, M. Van Velzen, B. Van der Horst, D. Vethaak, Chemosphere, 2002, 49, 97.

    Article  CAS  PubMed  Google Scholar 

  9. N.R. Kadasala, B. Narayanan, Y. Liu, Asian Dev. Policy Rev., 2016, 4, 134.

    Article  Google Scholar 

  10. C.D. Kinch, K. Ibhazehiebo, J.H. Jeong, H.R. Habibi, D.M. Kurrasch, Proc. Natl. Acad. Sci. U.S.A., 2015, 772, 1475.

    Article  Google Scholar 

  11. G.P. Cao, T. Chen, Y.F. Zhuang, J. Fluoresc., 2013, 23, 641.

    Article  CAS  PubMed  Google Scholar 

  12. L.J. Dong, Z.Q. Tan, M. Chen, J.F. Liu, Anal. Methods, 2015, 7, 1380.

    Article  CAS  Google Scholar 

  13. F. Vela-Soria, O. Ballesteros, A. Zafra-Gomez, L. Ballesteros and A. Navalon, Anal. Bioanal. Chem., 2014, 406, 3773.

    Article  CAS  PubMed  Google Scholar 

  14. Y.X. Liu, X.C. Dong, P. Chen, Chem. Soc. Rev., 2012, 47, 2283.

    Article  Google Scholar 

  15. P. Bühlmann, E. Pretsch, E. Bakker, Chem. Rev., 1998, 98, 1593.

    Article  PubMed  Google Scholar 

  16. E. Bakker, Anal. Chem., 2016, 88, 395.

    Article  CAS  PubMed  Google Scholar 

  17. T. Sokalski, A. Ceresa, T. Zwickl, E. Pretsch, J. Am. Chem. Soc., 1997, 779, 11347.

    Article  Google Scholar 

  18. E.H. El-Naby and A.H. Kamel, Mater. Sci. Eng., C, 2015, 54, 217.

    Article  Google Scholar 

  19. A.H. Kamel, H.R. Galal, N.S. Awaad, Anal. Methods, 2018, 70, 5406.

    Article  Google Scholar 

  20. G.A. Crespo, Electrochim. Acta, 2017, 245, 1023.

    Article  CAS  Google Scholar 

  21. M. Cuartero and G.A. Crespo, Curr. Opin. Electrochem., 2018, 70, 98.

    Article  Google Scholar 

  22. M. Parrilla, M. Cuartero, G.A. Crespo, TrAC, Trends Anal. Chem., 2019, 770, 303.

    Article  Google Scholar 

  23. S.S.M. Hassan, E.M. Elnemma, A.H.K. Mohamed, Electroanalysis, 2005, 77, 2246.

    Article  Google Scholar 

  24. T. Wang, R. Liang, T. Yin, R. Yao, W. Qin, RSC Adv., 2016, 6, 73308.

    Article  CAS  Google Scholar 

  25. N.S. Abdalla, M.A. Youssef, H. Algarni, N.S. Awwad, A.H. Kamel, Molecules, 2019, 24, 712.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  26. A.E. Amr, M.A. Al-Omar, A.H. Kamel, E.A. Elsayed, Molecules, 2019, 24, 920.

    Article  Google Scholar 

  27. E. Bakker, J. Electrochem. Soc., 1996, 743, L83.

    Article  Google Scholar 

  28. J. Bobacka, Anal. Chem., 1999, 77, 4932.

    Article  Google Scholar 

  29. M. Fibbioli, K. Bandyopadhyay, S.G. Liu, L. Echegoyen, O. Enger, F. Diederich, D. Gingery, P. Buhlmann, H. Persson, U.W. Suter, E. Pretsch, Chem. Mater., 2002, 74, 1721.

    Article  Google Scholar 

Download references

Acknowledgments

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University, Abha, Saudi Arabia for funding this work through General Research Project under grant number G.R.P.1/16/38 (Bioinorganic Chemistry Research Group).

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, King Khalid University, Abha, 61413, Saudi Arabia

    Hisham S. M. Abd-Rabboh

  2. Department of Chemistry, Faculty of Science, Ain Shams University, Abbassia, 11566, Cairo, Egypt

    Hisham S. M. Abd-Rabboh & Ayman H. Kamel

Authors
  1. Hisham S. M. Abd-Rabboh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ayman H. Kamel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hisham S. M. Abd-Rabboh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abd-Rabboh, H.S.M., Kamel, A.H. Novel Potentiometric Screen-printed Carbon Electrodes for Bisphenol S Detection in Commercial Plastic Samples. ANAL. SCI. 36, 1359–1363 (2020). https://doi.org/10.2116/analsci.20P143

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.20P143

Keywords

Search

Navigation