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Simultaneous Spectrophotometric Determination of p-Benzoquinone and Chloranil after Microcrystalline Naphthalene Extraction by Using Genetic Algorithm-Based Wavelength Selection-Partial Least Squares Regression

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Abstract

Microcrystalline naphthalene extraction has been used for the preconcentration of p-benzoquinone and tetrachloro-p-benzoquinone (chloranil), after their reaction by aniline, and later simultaneous spectrophotometric analysis by genetic algorithm-partial least squares (GA-PLS) calibration. The chemical variables affecting the analytical performance of the methodology were studied and optimized. Under the optimum conditions i.e., [aniline] = 0.05 M and [naphthalene] = 2.2% (w/v), preconcentration of 25 ml of sample solution permitted the detection of 0.32 and 0.23 μg ml−1 for p-benzoquinone and chloranil, respectively. The predictive abilities of partial least squares regression (PLS) and genetic algorithm-partial least squares regression (GA-PLS) were examined for simultaneous determination of two quinones. The GA-PLS shows superiority over other PLS methods due to the wavelength selection in PLS calibration using a genetic algorithm without loss of prediction capacity, provides useful information about the chemical system.

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Authors and Affiliations

  1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Zanjan, 45195-159, Iran

    Hamid Abdollahi & Leila Bagheri

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  1. Hamid Abdollahi
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  2. Leila Bagheri
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Correspondence to Hamid Abdollahi.

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Abdollahi, H., Bagheri, L. Simultaneous Spectrophotometric Determination of p-Benzoquinone and Chloranil after Microcrystalline Naphthalene Extraction by Using Genetic Algorithm-Based Wavelength Selection-Partial Least Squares Regression. ANAL. SCI. 20, 1701–1706 (2004). https://doi.org/10.2116/analsci.20.1701

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  • DOI: https://doi.org/10.2116/analsci.20.1701

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