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Measurement of Circular Dichroism Spectra of Liquid/Liquid Interface by Centrifugal Liquid Membrane Method

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Abstract

The direct measurement of the circular dichroism (CD) spectra of liquid/liquid interface has been achieved for the first time by the centrifugal liquid membrane (CLM) method combined with a conventional CD spectropolarimetry. In the sample chamber of the CD spectropolarimeter, a cylindrical glass cell containing small amounts of organic and aqueous phases was rotated at ca. 7000 rpm to generate a two-phase liquid membrane with a high specific interfacial area. The CD spectra of the J-aggregate of protonated 5,10,15,20-tetraphenylporphyrin formed at the toluene/sulfuric acid interface in the rotating cell have been measured. The results demonstrated the novelty and advantages of this method.

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References

  1. H. Watarai, S. Tsukahara, H. Nagatani, and A. Ohashi, Bull. Chem. Soc. Jpn., 2003, 76, 1471.

    Article  CAS  Google Scholar 

  2. K. Fujiwara, H. Monjushiro, and H. Watarai, Chem. Phys. Lett., 2004, 349.

    Google Scholar 

  3. H. Nagatani and H. Watarai, Anal. Chem., 1998, 70, 2860.

    Article  CAS  Google Scholar 

  4. H. Nagatani and H. Watarai, Chem. Lett., 1999, 701.

    Google Scholar 

  5. A. Ohashi and H. Watarai, Langmuir, 2002, 18, 10292.

    Article  CAS  Google Scholar 

  6. X. Huang, K. Nakanishi, and N. Berova, Chirality, 2000, 12, 237.

    Article  CAS  Google Scholar 

  7. O. Ohno, Y. Kaizu, and H. Kobayashi, J. Chem. Phys., 1993, 99, 4128.

    Article  CAS  Google Scholar 

  8. J. M. Ribo, J. Crusats, F. Sagues, J. Claret, and R. Rubires, Science, 2001, 292, 2063.

    Article  CAS  Google Scholar 

  9. L. Zhang, Q. Lu, and M. Liu, J. Phys. Chem. B, 2003, 107, 2565.

    Article  CAS  Google Scholar 

  10. A. S. R. Koti and N. Periasamy, Chem. Mater., 2003, 15, 369.

    Article  CAS  Google Scholar 

  11. J. Crusats, J. Claret, I. Diez-Perez, Z. El-Hachemi, H. Garcia-Ortega, R. Rubires, F. Sagues, and J. M. Ribo, Chem. Commun., 2003, 1588.

    Google Scholar 

  12. D. L. Akins, H.-R. Zhu, and C. Guo, J. Phys. Chem., 1994, 98, 3612.

    Article  CAS  Google Scholar 

  13. N. C. Maiti, S. Mazumdar, and N. Periasamy, J. Phys. Chem. B, 1998, 102, 1528.

    Article  CAS  Google Scholar 

  14. H. Watarai and Y. Chida, Anal. Sci., 1994, 10, 105.

    Article  CAS  Google Scholar 

  15. Y. Moriya, N. Ogawa, T. Kumabe, and H. Watarai, Chem. Lett., 1998, 221.

    Google Scholar 

  16. A. Ohashi and H. Watarai, Chem. Lett., 2001, 1238.

    Google Scholar 

  17. Y. Yulizar and H. Watarai, Bull. Chem. Soc. Jpn., 2003, 76, 1379.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Osaka University, 1-1, Machikaneyama-cho, Toyonaka, Osaka, 560-0043, Japan

    Sayaka Wada, Hideaki Monjushiro & Hitoshi Watarai

  2. Faculty of Engineering and Resource Science, Akita University, 1-1, Tegatagakuen-cho, Akita, 010-8502, Japan

    Kazuhiko Fujiwara

Authors
  1. Sayaka Wada
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  2. Kazuhiko Fujiwara
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  3. Hideaki Monjushiro
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  4. Hitoshi Watarai
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Correspondence to Hitoshi Watarai.

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Wada, S., Fujiwara, K., Monjushiro, H. et al. Measurement of Circular Dichroism Spectra of Liquid/Liquid Interface by Centrifugal Liquid Membrane Method. ANAL. SCI. 20, 1489–1491 (2004). https://doi.org/10.2116/analsci.20.1489

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  • DOI: https://doi.org/10.2116/analsci.20.1489

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