Abstract
A new ammonia optical sensor was designed using bis(acetylacetoneethylendiamine)tributylphosphin cobalt(III) tetraphenylborate complex, coated on transparent triacetylcellulose film as membrane. The change in the absorbance of the optode at the maximum wavelength of 408 nm was related to ammonia concentration in aqueous samples. A buffer solution with a pH of 9 (sodium borate–HCl) was used. The optode was fully regenerated in pH au]2._The linear dynamic range for determination of ammonia was 3.3 × 10–4 to 6.9 × 10–3 mol l–1 with a detection limit of 5.0 × 10–5 mol l–1 and a response time range of 4–6 min. This membrane was successfully applied for determination of ammonia in drinking water.
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Y. Aoi, Y. Shiramasa, S. Tsuneda, A. Hirata, A. Kitayama, and T. Nagamune, Water Sci. Tec., 2002, 46, 439.
C.-H. Wu, L. Scampavia, J. Ruzicka, and B. Zamost, Analyst, 2001, 126, 291.
W. E. Holben, K. Noto, T. Sumino, and Y. Suwa, Appl. Environ. Microbiol., 1998, 64(7), 2528.
A. R. Barnes and J. K. Sugden, Pharm. Acta Helv., 1990, 65, 258.
M. D. L. Torre, M. D. L. Castero, and M. Valcarcel, Talanta, 1992, 39, 869.
T. K. V. Krawczyk and M. Trajanowicz, Anal. Sci., 1992, 8, 329.
J.-Z. Zhang, P. B. Ortner, C. Fischer, and L. Moore, EPA’s Manual, Suplement I, EPA/600/R-97/072, September 1997.
T. Werner, I. Klimant, and O. S. Wolfbesi, Analyst, 1995, 120, 1627.
N. Hata, K. Teraguchi, M. Yamaguchi, J. Kasahara, S. Tataguchi, and K. Goto, Microchim. Acta Helv., 1990, 65, 258.
S. Simhoney and A. Katzir, Appl. Phys. Lett., 1985, 47, 1241.
M. E. Meyerhoff and R. E. Robins, Anal. Chem., 1985, 52, 2383.
D. J. David, M. C. Willson, and D. S. Ruffin, Anal. Lett., 1976, 9, 389.
Y.-S. Lee, B.-S. Joo, N.-J. Choi, J.-O. Lim, J.-S. Huh, and D.-D. Lee, Sens. Actuators B: Chemical, 2003, 93, 148.
O. S. Wolfbis (ed.), “Fiber Optic Chemical Sensors and Biosensors”, 1991, Vols. 1 and 2, CRC Press, Boca Raton, FL.
T. D. Rhines and M. A. Arnold, Anal. Chem. Acta, 1990, 231, 231.
G. Gauglitz and G. Kraus, Fresenius J. Anal. Chem., 1993, 349, 572.
S. Ozawa, P. Hauser, K. Seiler, S. S. S. Tan, W. E. Morf, and W. Simon, Anal. Chem., 1991, 63, 640.
S. J. West, S. Ozawa, K. Seiler, S. S. S. Tan, and W. Simon, Anal. Chem., 1992, 64, 533.
M. R. Fuh, L. W. Burgess, T. Hirschfeld, G. D. Christian, and F. Wang, Analyst, 1987, 112, 1159.
E. Urbano, H. Offenbacher, and O. S. Wolfbeis, Anal. Chem., 1984, 56, 427.
M. J. Goldfinch and C. R. Lowe, Anal. Biochem., 1980, 109, 216.
B. P. H. Schaffar and O. S. Wolfbeis, Anal. Chim. Acta, 1989, 217, 1.
B. P. H. Schaffar and O. S. Wolfbeis, and A. Leitner, Analyst, 1988, 113, 693.
U. J. Krull, R. S. Brown, R. F. Debono, and B. D. Hougham, Talanta, 1988, 35, 129.
R. R. Smardzewski, Talanta, 1988, 35, 95.
O. S. Wolfbis, L. J. Weis, M. J. P. Leiner, and W. E. Ziegler, Anal. Chem., 1988, 60, 2028.
A. J. Guthrie, R. Narayanaswamy, and N. A. Welti, Talanta, 1988, 35, 157.
D. C. Ashworth, H. P. Huang, R. Narayanaswamy, and R. E. Sutheriand, Anal. Chim. Acta, 1988, 213, 251.
J. F. Alder, D. C. Ashworth, R. Narayanaswamy, R. E. Moss, and I. O. Sutheriand, Analyst, 1987, 112, 1191.
T. C. Warner, J. G. Cummings, and W. R. Seitz, Anal. Chem., 1989, 61, 211.
Y. Kawabata, R. Tahara, T. Imasaka, and N. Ishibashi, Anal. Chim. Acta, 1988, 212, 267.
F. V. Bright, G. E. Poirier, and G. M. Hieftje, Talanta, 1988, 35, 113.
P. Y. F. Li and R. Narayanaswamy, Analyst, 1989, 114, 1191.
K. Suzuki, K. Tohda, Y. Tanda, H. Ohzora, S. Nishihama, H. Inoue, and T. Shirai, Anal. Chem., 1989, 61, 382.
M. K. Carroll, F. V. Bright, and G. M. Hieftje, Anal. Chem., 1989, 61, 1768.
W. P. Carey, M. D. Degrandpre, and B. S. Jorgensen, Anal. Chem., 1989, 61, 1647.
R. L. Cook, R. C. Macduff, and A. F. Sammells, Anal. Chim. Acta, 1989, 226, 153.
F. L. Dikert, S. K. Schreiner, G. R. Mages, and H. Kimmel, Anal. Chem., 1989, 61, 2306.
H. E. Posch, O. S. Wolfbeis, and J. Pusterhofer, Talanta, 1988, 35, 89.
G. Tauzher, G. Mestroni, A. Puxeddu, R. Costanzo, and G. Costa, J. Chem. Soc., A, 1971, 2504.
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Absalan, G., Soleimani, M., Asadi, M. et al. Constructing a New Optical Sensor for Monitoring Ammonia in Water Samples Using Bis(acetylacetoneethylendiamine)-tributylphosphin Cobalt(III) Tetraphenylborate Complex-Coated Triacetylcellulose. ANAL. SCI. 20, 1433–1436 (2004). https://doi.org/10.2116/analsci.20.1433
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DOI: https://doi.org/10.2116/analsci.20.1433