Skip to main content
SpringerLink
Log in

Solvent Extraction of Lanthanoid and Yttrium Ions with Poly(oxyethylene)alkylphenylether

  • Original Paper
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

Solvent extraction of lanthanoid and yttrium ions(M3+) was investigated in a water-dichloroethane system using poly(oxyethylene)-type nonionic surfactants such as Triton X-100 and Triton X-405(L) and picrate ion(A-) as extraction agent and pairing anion, respectively. The result of extraction studies at various extraction agent concentrations and at various picrate ion concentrations, suggested that the composition of the extracted species was MLA3. Among the lanthanoid ions investigated, the ions such as Nd3+, Sm3+, Eu3+, and Gd3+ gave relatively larger distribution ratios than the other lanthanoid ions, while the yttrium ion was the least extractable among the metal ions investigated. The distribution ratio with extraction agent Triton X-405 was about ten times larger than those with Triton X-100.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Sotobayashi, T. Suzuki and S. Tonouchi, Chem. Lett., 1976, 585.

    Google Scholar 

  2. T. Sotobayashi, T. Suzuki and K. Yamada, Chem. Lett., 1976, 77.

    Google Scholar 

  3. T. Sotobayashi, T. Suzuki and H. Kudo, J. Radioanal. Chem., 36, 145 (1977).

    Article  CAS  Google Scholar 

  4. M. Otomo and Y. Wakamatsu, Bunseki Kagaku, 17, 764 (1968).

    Article  CAS  Google Scholar 

  5. L. M. Tsay, J. S. Shih and S. C. Wu, Analyst [London], 108, 1108 (1983).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Industrial Chemistry, Kumamoto Institute of Technology, Kumamoto, 860, Japan

    Isao Yoshida, Ryo’ichi Takeshita & Keihei Ueno

  2. Department of Organic Synthesis, Faculty of Engineering, Kyushu University, Hakozaki, Fukuoka, 812, Japan

    Makoto Takagi

Authors
  1. Isao Yoshida
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ryo’ichi Takeshita
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Keihei Ueno
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Makoto Takagi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yoshida, I., Takeshita, R., Ueno, K. et al. Solvent Extraction of Lanthanoid and Yttrium Ions with Poly(oxyethylene)alkylphenylether. ANAL. SCI. 2, 53–56 (1986). https://doi.org/10.2116/analsci.2.53

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.2.53

Keywords

Search

Navigation