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Crystal Structure of Dissymmetrically Trihydrated N, N′,N″-Tribenzoylmelamine (TBM)

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Abstract

In the crystal structure of TBM-trihydrate three waters of crystallization were found to locate dissymmetrically. Thus, one of them forms a chelated ring with the neighboring C=O and N–H of TBM. Two other ones bind each other through hydrogen bonding and two sets of which form a cyclic dimer by hydrogen bonding (namely, water-tetramer). A C=O group binds by hydrogen bonding to each of the tetrameric water. The spatial volume occupied by water-teramer appears to be sufficient for complexation with organic molecules.

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References

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Authors and Affiliations

  1. Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Fukui University, 9-1 Bunkyo 3-chome, Fukui, 910-8507, Japan

    Ichiro Takahashi, Shigeki Kamimura, Minoru Hatanaka & Hidehiko Kitajima

  2. X-ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubara-cho, Akishima, Tokyo, 196-8666, Japan

    Akihito Yamano

  3. Faculty of Pharmaceutical Sciences, Kanazawa University, 13-1 Takara-machi, Kanazawa, 920-0934, Japan

    Tomihisa Ohta & Shinzo Hosoi

Authors
  1. Ichiro Takahashi
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  2. Shigeki Kamimura
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  3. Minoru Hatanaka
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  4. Hidehiko Kitajima
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  5. Akihito Yamano
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  6. Tomihisa Ohta
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  7. Shinzo Hosoi
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Corresponding author

Correspondence to Shinzo Hosoi.

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Takahashi, I., Kamimura, S., Hatanaka, M. et al. Crystal Structure of Dissymmetrically Trihydrated N, N′,N″-Tribenzoylmelamine (TBM). ANAL. SCI. 19, 807–808 (2003). https://doi.org/10.2116/analsci.19.807

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  • DOI: https://doi.org/10.2116/analsci.19.807

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