Skip to main content
SpringerLink
Log in

Crystal Structure of a Binuclear Polymeric Self-Assembled Lead(II) Complex

  • Instrumental Achievement
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A polymeric self-assembled complex {[Pb(pydc)(pydc·H2)(H2O)2]2}n is prepared from the complexation of a novel pyridine containing self-assembling system, LH2, [pydaH2]2+[pydc]2–(pyda = 2,6-pyridindiamine and pydcH2 = 2,6-pyridinedicarboxilic acid) and lead(II) nitrate in 84% yield. The characterization was performed using X-ray crystallography. The crystal system is triclinic with space group P–1 and two molecules per unit cell. The unit cell dimensions are a = 6.913(2)Å, b = 10.687(4)Å and c = 11.182(4)Å with α = 92.805(6)°, β = 101.821(6)° and γ = 95.688(6)°. The final Rvalue is 0.0373 for 4633 reflections measured. This compound is a nine-coordinate binuclear complex with two metal fragments linked via the central four-membered Pb2O2 ring. The crystal also contains a neutral [pydc·H2] molecule, that form hydrogen and coordination bonds that dominate the crystal packing, by forming layers of molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. J. C. Mac Donald, P. C. Dorrestein, M. M. Pilley, M. M. Foote, J. L. Lundburg, R. W. Henning, A. J. Schultz, and L. J. Manson, J. Am. Chem. Soc., 2000, 112, 11692.

    Google Scholar 

  2. M. Ranjbar, H. Aghabozorg, A. Moghimi, and A. Yanovsky, Anal. Sci., 2001, 17, 1469

    Article  CAS  Google Scholar 

  3. M. Ranjbar, A. Moghimi, H. Aghabozorg, and G. P. A. Yap, Anal. Sci., 2002, 18, 219

    Article  CAS  Google Scholar 

  4. M. Ranjbar, H. Aghabozorg, A. Moghimi, and A. Yanovsky, Z. Kristallographic, New Crystal Structure, 2001, 216, 626.

    CAS  Google Scholar 

  5. L. Shimoni-Livny, J. P. Glusker, and C. W. Bock, Inorg. Chem., 1998, 37, 1853

    Article  CAS  Google Scholar 

  6. J. M. Harrowfield, H. Miyamae, B. W. Skelton, A. A. Soudi, and A. H. White, Aust. J. Chem., 1996, 49 1121

    Article  CAS  Google Scholar 

  7. J. M. Harrowfield, H. Miyamae, B. W. Skelton, A. A. Soudi, and A. H. White, Aust. J. Chem., 1996, 49, 1127.

    Article  CAS  Google Scholar 

  8. A. Moghimi, M. Ranjbar, H. Aghabozorg, J. Jalali, M. Shamsipur G. P. A. Yap, and H. Rahbarnoohi, J. Mol. Struct., 2002, 605, 133.

    Article  CAS  Google Scholar 

  9. N. W. Alcock, N. Herron, and P. Moor, J. Chem. Soc., Dalton Trans., 1979, 1486.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Industries, Iranian Research Organization Science and Technology, Tehran, Iran

    Maryam Ranjbar

  2. Department of Chemistry, University of Imam Hossein, Tehran, Iran

    Abolghasem Moghimi

  3. Department of Chemistry, Teacher Training University, Tehran, Iran

    Hossein Aghabozorg

Authors
  1. Maryam Ranjbar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Abolghasem Moghimi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hossein Aghabozorg
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hossein Aghabozorg.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ranjbar, M., Moghimi, A. & Aghabozorg, H. Crystal Structure of a Binuclear Polymeric Self-Assembled Lead(II) Complex. ANAL. SCI. 19, 803–804 (2003). https://doi.org/10.2116/analsci.19.803

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.19.803

Search

Navigation