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Crystal Structure of 1β-Hydroxy-β-homopipitzolone (9-Hydroxy-2,6,9-trimethyltricyclo[6,3,1,01,6]dodeca-5,10,11,12-tetraone)

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Abstract

C15H18O5 is orthorhombic, P212121. The unit-cell dimensions at 293 K are a = 6.526(3), b = 10.247(4), c = 21.008(13)Å, V = 1404.8(12)Å3, Dx = 1.316 g/cm3, and Z = 4. The R value is 0.044 for 1288 observed reflections. The A, B and C rings adopt chair, twist, and half-chair conformations. The absolute configuration is inferred from the C6 stereochemistry of (+)-cedrol. The crystal structure is stabilized by an O–H•••O hydrogen bond and van der Waals forces.

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References

  1. V. Mendoza, E. García, J. A. Guzmán, L. Chacon, E. Huipe, and S. V. Lindeman. XXVIII Congreso Mexicano de Qufmica Pura y Aplicada, Puerto Vallarta, Jal., México, 1977, Abstract No. 261.

    Google Scholar 

  2. V. Mendoza, E. García, M. Reyes, and J. A. Guzmán, XXIV Congreso Mexicano de Química Pura y Aplicada, Querétaro, Qro., México, 1977, Abstract No. 161.

    Google Scholar 

  3. M. Nardelli, J. Appl. Cryst, 1995, 28, 659.

    Article  CAS  Google Scholar 

  4. G. Stork and F. H. Clarke Jr., J. Am. Chem. Soc, 1961, 83, 3114.

    Article  CAS  Google Scholar 

  5. V. Amirthalingam, D. F. Grant, and A. Senol, Acta Crystallogr., 1972, B28, 1340.

    Article  Google Scholar 

  6. M. Soriano-García, F. Walls, and R. A. Toscano, Acta Crystallogr., 1986, C42, 329.

    Google Scholar 

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Authors and Affiliations

  1. Instituto de Química, UNAM, Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510, México D. F., México

    Manuel Soriano-GarcíA

  2. Instituto Tecnológico, Av. Tecnológico 1500, C. P. 58120, Morelia, Mich., México

    Ezequiel Huipe-Nava

  3. Instituto de Investigaciones Químico-Biológicas, U. M. S. N. H., Morelia Mich., México

    Virgilio Mendoza González & Esther García Garibay

Authors
  1. Manuel Soriano-GarcíA
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  2. Ezequiel Huipe-Nava
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  3. Virgilio Mendoza González
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  4. Esther García Garibay
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Soriano-GarcíA, M., Huipe-Nava, E., González, V.M. et al. Crystal Structure of 1β-Hydroxy-β-homopipitzolone (9-Hydroxy-2,6,9-trimethyltricyclo[6,3,1,01,6]dodeca-5,10,11,12-tetraone). ANAL. SCI. 19, 801–802 (2003). https://doi.org/10.2116/analsci.19.801

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  • DOI: https://doi.org/10.2116/analsci.19.801

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