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Comparative Study of the Response of Membrane Electrodes Based on Calix[6]arene and Calix[8]arene Derivatives to Organic Ammonium Ions

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Abstract

p-tert-Butylcalix[8]arene-octaacetic acid octaethyl ester and calix[8]arene-octaacetic acid octaethyl ester well recognized 2-phenylethylamine and phenylalanine methyl ester compared with the corresponding calix[6]arene derivatives. Moreover, the calix[8]arene derivatives, especially one having tert-butyl groups, gave better selectivity against biologically active amines having a complicated structure, such as norephedrine. We considered the interaction between calixarenes and organic ammonium ions from the viewpoint of molecular symmetries.

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Authors and Affiliations

  1. Faculty of Pharmaceutical Sciences, Okayama University, Okayama, 700-8530, Japan

    Takashi Katsu & Nozomi Okaki

  2. Criminal Investigation Laboratory, Okayama Prefectural Police Headquarters, 1-3-2, Tonda-cho, Okayama, 700-0816, Japan

    Kiyoyuki Watanabe & Kiyoka Takaishi

  3. Tokyo Kasei Kogyo Co., Ltd., 6-15-9, Toshima, Kita-ku, Tokyo, 114-0003, Japan

    Hirochika Yokosu

Authors
  1. Takashi Katsu
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  2. Nozomi Okaki
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  3. Kiyoyuki Watanabe
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  4. Kiyoka Takaishi
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  5. Hirochika Yokosu
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Corresponding author

Correspondence to Takashi Katsu.

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Katsu, T., Okaki, N., Watanabe, K. et al. Comparative Study of the Response of Membrane Electrodes Based on Calix[6]arene and Calix[8]arene Derivatives to Organic Ammonium Ions. ANAL. SCI. 19, 771–774 (2003). https://doi.org/10.2116/analsci.19.771

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  • DOI: https://doi.org/10.2116/analsci.19.771

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