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A Sensitive Electrochemiluminescence Sensor for Brilliant Blue FCF Using Ru(bpy)32+ Immobilized Zn-MOF

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Abstract

A novel electrochemiluminescence (ECL) sensor for detection of brilliant blue FCF (BB) has been developed using Ru@ Zn-MOF/nafion modified GCE (glass carbon electrode) in this research. Different from conventional method for usage of Ru(bpy)32+ in solution-phase, Ru(bpy)32+ here was immobilized on a zinc-metal-organic-framework (Zn-MOF). After adding BB, a significant quenching phenomenon of ECL intensity was observed. The behavior of BB on the quenching effect of Ru(bpy)32+/Zn-MOF in different conditions was investigated thoroughly and the detection limit was achieved to 2.5 × 10−8 M in an optimized condition. Furthermore, the interference of some conventional ions and amino acids to the detection of BB was also investigated. Additionally, the composite showed a good effect on the detection of BB in commercial samples. The proposed sensor provided a promising platform for food safety analysis, environmental monitoring and clinical testing.

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Acknowledgments

The authors are grateful to the financial support by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (18KJB150001), the National Natural Science Foundation of China (51574047) and the Foundation of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology (BM2012110).

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China

    Xueling Shan, Yuting Pan, Wenchang Wang & Zhidong Chen

  2. School of Chemistry and Material Engineering, Changzhou Vocational Institute of Engineering, Changzhou, 213164, China

    Xiaohui Chen

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  1. Xueling Shan
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  2. Yuting Pan
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  3. Xiaohui Chen
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  4. Wenchang Wang
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  5. Zhidong Chen
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Correspondence to Zhidong Chen.

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Shan, X., Pan, Y., Chen, X. et al. A Sensitive Electrochemiluminescence Sensor for Brilliant Blue FCF Using Ru(bpy)32+ Immobilized Zn-MOF. ANAL. SCI. 35, 639–644 (2019). https://doi.org/10.2116/analsci.18P572

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  • DOI: https://doi.org/10.2116/analsci.18P572

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