Skip to main content
SpringerLink
Log in

Determination of Dissolved Silica in Seawater by Ion-exclusion Chromatography with Post-column Derivatization/ Silicomolybdenum Yellow Detection

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The determination of dissolved silica in seawater was investigated by an ion-exclusion chromatography with a post-column derivatization/silicomolybdenum yellow method. To determine dissolved silica in seawater accurately, the experimental conditions, such as the volume of a reaction coil, the eluent concentration and the sample dilution factor, were optimized. This is the first report that has examined the details of the experimental condition for the measurement of dissolved silica in seawater by ion-exclusion chromatography with silicomolybdenum-yellow detection. The developed method was compared with the widely used continuous flow analysis and an ion-exclusion chromatography isotope dilution inductively coupled plasma mass spectrometry, which is a primary method of measurement. The analytical results by the three methods were in good agreement, considering the expanded uncertainty with a coverage factor, 2. The validity of the three methods was confirmed with each other. The developed method can give a quantitative value with less than 1% of the expanded uncertainty, and can be used for the determination of dissolved silica in candidate reference materials having a seawater matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Knap, A. Michaels, A. Close, H. Ducklow, and A. Dickson, “Protocols for the Joint Global Ocean Flux Study (JGOFS) Core Measurements”, 1996, JGOFS Report No. 19, JGOFS, Woods Hole.

    Google Scholar 

  2. M. Aoyama, H. Ota, M. Kimura, T. Kitao, H. Mitsuda, A. Murata, and K. Sato, Anal. Sci., 2012, 28, 911.

    Article  CAS  PubMed  Google Scholar 

  3. B. C. Reynolds, M. Frank, and A. N. Halliday, Earth Planet Sci. Lett., 2006, 244, 431.

    Article  CAS  Google Scholar 

  4. Certificates for NMIJ CRM 7601-a, 7602-a and 7603-a, Compilation prepared by National Metrology Institute of Japan (NMIJ), https://www.nmij.Jp/english/service/C/CRM_Catalog_(JE)160901.pdf.

  5. N. Nonose, C. Cheong, Y. Ishizawa, T. Miura, and A. Hioki, Anal. Chim. Acta, 2014, 840, 10.

    Article  CAS  PubMed  Google Scholar 

  6. L. Yang, E. Pagliano, and Z. Mester, Anal. Chem., 2014, 86, 3222.

    Article  CAS  PubMed  Google Scholar 

  7. M. J. T. Milton and T. J. Quinn, Metrologia, 2001, 38, 289.

    Article  CAS  Google Scholar 

  8. C. Cheong, N. Nonose, T. Miura, and A. Hioki, Accredit. Qual. Assur., 2014, 19, 31.

    Article  CAS  Google Scholar 

  9. K. Grasshoff, K. Kremling, and M. Ehrhardt, “Methods of Seawater Analysis”, 1999, Wiley-VCH, New York, 193.

    Book  Google Scholar 

  10. K. Bakker, J. Ooijen, E. Weerlee, and E. Epping, “Comparability of Nutrients in the World’s Ocean”, ed. M. Aoyama, A. G. Dickson, D. J. Hydes, A. Murata, J. R. Oh, P. Roose, and E. M. S. Woodward, 2010, Mother Tank, Tsukuba, 127.

  11. D. M. Laurence, Sci. Total Environ., 1986, 49, 27.

    Article  Google Scholar 

  12. H. P. Hansen and F. Koroleff, “Methods of Seawater Analysis”, ed. K. Grasshoff, K. Kremling, and M. Ehrhardt, 3rd ed., 1999, Wiley-VCH, New York, 170.

  13. D. J. Hydes, M. Aoyama, A. Aminot, K. Bakker, S. Becker, S. Coverly, A. Daniel, A. G. Dickson, O. Grosso, R. Kerouel, J. van Ooijien, K. Sato, T. Tanhua, E. M. S. Woodward, and J. Z. Zhang, “The GO-SHIP Repeat Hydrography Manual: a Collection of Expert Reports and Guidelines”, ed. E. M. Hood, C. L. Sabine, and B. M. Sloyan, 2010, IOCCP Report No. 14, ICPO Publication Series No. 134, GO-SHIP, Paris.

  14. C. Cheong, T. Miura, and A. Hioki, Abstracts of the 77th Conference on Analytical Chemistry (in Japanese), 2017, Kyoto, 36.

  15. H. Sakai, T. Fujiwara, and T. Kumamaru, Anal. Chim. Acta, 1995, 302, 173.

    Article  CAS  Google Scholar 

  16. N. Nakatani, D. Kozaki, W. Masuda, N. Nakagoshi, K. Hasebe, M. Mori, and K. Tanaka, Anal. Chim. Acta, 2008, 619, 110.

    Article  CAS  PubMed  Google Scholar 

  17. N. Nakatani, W. Masuda, D. Kozaki, M. Mori, K. Hasebe, N. Nakagoshi and K. Tanaka, Bunseki Kagaku, 2009, 58, 305.

    Article  CAS  Google Scholar 

  18. N. Nakatani, D. Kozaki, M. Mori, and K. Tanaka, Anal. Sci., 2012, 28, 845.

    Article  CAS  PubMed  Google Scholar 

  19. N. Gros, Water, 2013, 5, 659.

    Article  CAS  Google Scholar 

  20. M. Ikedo, M. Mori, K. Kurachi, W. Hu, and K. Tanaka, Anal. Sci., 2006, 22, 117.

    Article  CAS  PubMed  Google Scholar 

  21. K. Grasshoff, Deep-Sea Res., 1964, 11, 597.

    CAS  Google Scholar 

  22. R. Ramachandran and P. K. Gupta, Anal. Chim. Acta, 1985, 172, 307.

    Article  CAS  Google Scholar 

  23. Japan Industrial Standards JIS K 0124:2011, “General Rules for High Performance Liquid Chromatography.”

  24. JCGM 100: 2008, “Evaluation of Measurement Data— Guide to the Expression of Uncertainty in Measurement”, 2008, Working Group 1 of the Joint Committee for Guides in Metrology, Paris, 47, http://www.bipm.org/utils/common/documents/jcgm/JCGM_100_2008_E.pdf.

    Google Scholar 

  25. J. N. Miller, Analyst, 1991, 116, 3.

    Article  CAS  Google Scholar 

  26. J. O. D. Beer, T. R. D. Beer, and L. Goeyens, Anal. Chim. Acta, 2007, 584, 57.

    Article  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, Ibaraki, 305-8563, Japan

    Chikako Cheong, Yoshiyasu Yamauchi & Tsutomu Miura

Authors
  1. Chikako Cheong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yoshiyasu Yamauchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tsutomu Miura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Chikako Cheong.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cheong, C., Yamauchi, Y. & Miura, T. Determination of Dissolved Silica in Seawater by Ion-exclusion Chromatography with Post-column Derivatization/ Silicomolybdenum Yellow Detection. ANAL. SCI. 34, 477–481 (2018). https://doi.org/10.2116/analsci.17P508

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.17P508

Keywords

Search

Navigation