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Anion Selectivities of Dibutyltin Dihalides as Neutral Carriers for Ion-Selective Electrodes

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Abstract

Di-n-butyltin dihalides (Bu2SnY2, Y=Cl, I, OMe) behaved as neutral carriers for anion-selective electrodes. A variety of selectivity patterns have been obtained by using Bu2SnY2 which differ in the electronegative substituents Y on the Sn atom. However, all electrodes containing Bu2SnY2 provided the highest degree of selectivity for the SCN- ion. The interaction of Bu2SnY2 with the SCN- ion was studied in the organic solution by means of 13C NMR spectroscopy. In the case of the addition of NaSCN, a significant increase of the value of 1J(119Sn–13Ca) was observed in the 2.0 M CDCl3 solution of Bu2SnCl2.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, Omiya, Asahi, Osaka, 535-8585, Japan

    Takayo Moriuchi-Kawakami, Hiroshi Aoto, Naotake Takeda, Keiichi Fujimori & Yasuhiko Shibutani

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  1. Takayo Moriuchi-Kawakami
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  2. Hiroshi Aoto
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  3. Naotake Takeda
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  4. Keiichi Fujimori
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  5. Yasuhiko Shibutani
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Moriuchi-Kawakami, T., Aoto, H., Takeda, N. et al. Anion Selectivities of Dibutyltin Dihalides as Neutral Carriers for Ion-Selective Electrodes. ANAL. SCI. 16, 303–306 (2000). https://doi.org/10.2116/analsci.16.303

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  • DOI: https://doi.org/10.2116/analsci.16.303

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