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Potentiometric Responses of Expanded Porphyrin Incorporated Liquid Membrane Electrodes toward a Series of Inorganic and Organic Anions

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Abstract

The potentiometric responses of liquid membrane electrodes based on expanded porphyrins such as sapphyrin, rubyrin and triphenylrosarin, toward a series of organic carboxylates and inorganic anions were investigated. pH titration of these expanded porphyrin based electrodes with and without a guest anion in the sample solution showed that protonation of the expanded porphyrins at the surface of the electrode membrane is a prerequisite for accommodating the guest anions and yielding their potential responses. The electrodes strongly responded to benzoates, but rather less to inorganic anions and saturated aliphatic organic carboxylates. The selectivity sequences for the sapphyrin based electrode were found in some cases to deviate from the Hofmeister series; fluoride preference over chloride and bromide is particularly noted. Interesting responses were observed by the electrodes for discriminating geometrical isomers: hydrogenmaleate over hydrogenfumarate, and positional isomers: phthalate over iso- and terephthalate and trichloroacetate over di- and mono-chloroacetates.

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Authors and Affiliations

  1. Division of Environmental Conservation, Graduate School of Environmental Science, Hokkaido University, Sapporo, 060, Japan

    Xiao Ming Lin

  2. Department of Chemistry, Faculty of Science, Ochanomizu University, Bunkyo, Tokyo, 152, Japan

    Kayoko Umezawa

  3. Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo, Tokyo, 113, Japan

    Koji Tohda & Yoshio Umezawa

  4. Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, 78712, USA

    Hiroyuki Furuta & Jonathan L. Sessler

  5. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, 606, Japan

    Hiroyuki Furuta

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  1. Xiao Ming Lin
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  2. Kayoko Umezawa
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  4. Hiroyuki Furuta
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  5. Jonathan L. Sessler
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  6. Yoshio Umezawa
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Lin, X.M., Umezawa, K., Tohda, K. et al. Potentiometric Responses of Expanded Porphyrin Incorporated Liquid Membrane Electrodes toward a Series of Inorganic and Organic Anions. ANAL. SCI. 14, 99–108 (1998). https://doi.org/10.2116/analsci.14.99

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  • DOI: https://doi.org/10.2116/analsci.14.99

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